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32805

Supelco

Mandipropamid

PESTANAL®, analytical standard

Synonym(s):

2-(4-Chlorophenyl)-N-[3-methoxy-4-(2-propynyloxy)phenethyl]-2-(2-propynyloxy)acetamide

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About This Item

Empirical Formula (Hill Notation):
C23H22ClNO4
CAS Number:
374726-62-2
Molecular Weight:
411.88
MDL number:
MFCD09751510
UNSPSC Code:
41116107
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

ClC1=CC=C(C(OCC#C)C(NCCC2=CC=C(OCC#C)C(OC)=C2)=O)C=C1

InChI

1S/C23H22ClNO4/c1-4-14-28-20-11-6-17(16-21(20)27-3)12-13-25-23(26)22(29-15-5-2)18-7-9-19(24)10-8-18/h1-2,6-11,16,22H,12-15H2,3H3,(H,25,26)

InChI key

KWLVWJPJKJMCSH-UHFFFAOYSA-N

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General description

Mandipropamid is a carboxylic acid amide, which belongs to the oomycete class of fungicides. It is found to be effective in controlling phytopathogens such as Plasmopara viticola on grapes and potato late blight caused by Phytophthora infestans.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Environment
GHS09

Signal Word

Warning

Hazard Statements

H410

Precautionary Statements

P273 - P391 - P501

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF9297
BCBW8925
BCBT4049
SZBD246XV
SZBC143XV

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Multicomponent reactions in fungicide research: The discovery of mandipropamid.
Lamberth C, et al.
Bioorganic & Medicinal Chemistry, 16(3), 1531-1545 (2008)
Guofeng Xu et al.
Environmental science and pollution research international, 27(32), 40148-40155 (2020-07-15)
Enantioselective monitoring of chiral fungicide mandipropamid enantiomers were carried out in grapes and wine-making process. The enantiomers of mandipropamid were separated on a Lux Cellulose-2 column and determined by ultra-high-performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS). The processing
Mandipropamid targets the cellulose synthase?like PiCesA3 to inhibit cell wall biosynthesis in the oomycete plant pathogen, Phytophthora infestans.
Blum M, et al.
Molecular Plant Pathology, 11(2), 227-243 (2010)
Vasileios Vangalis et al.
Journal of fungi (Basel, Switzerland), 6(4) (2020-12-11)
Woronin bodies are membrane-bound organelles of filamentous ascomycetes that mediate hyphal compartmentalization by plugging septal pores upon hyphal damage. Their major component is the peroxisomal protein Hex1, which has also been implicated in additional cellular processes in fungi. Here, we
Nikhilesh Dhar et al.
Plant disease, 104(1), 82-93 (2019-11-19)
The lettuce downy mildew pathogen, Bremia lactucae, is an obligate oomycete that causes extensive produce losses. Initial chlorotic symptoms that severely reduce the market value of the produce are followed by the appearance of white, downy sporulation on the abaxial
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