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M46705

Sigma-Aldrich

N-Methylformamide

99%

Synonym(s):

N-Formylmethylamine

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About This Item

Linear Formula:
HCONHCH3
CAS Number:
123-39-7
Molecular Weight:
59.07
Beilstein:
1098352
EC Number:
204-624-6
MDL number:
MFCD00003280
UNSPSC Code:
12352100
PubChem Substance ID:
329817991
NACRES:
NA.21

Assay

99%

form

liquid

refractive index

n20/D 1.432 (lit.)

bp

198-199 °C (lit.)

mp

−4 °C (lit.)

density

1.011 g/mL at 25 °C (lit.)

SMILES string

[H]C(=O)NC

InChI

1S/C2H5NO/c1-3-2-4/h2H,1H3,(H,3,4)

InChI key

ATHHXGZTWNVVOU-UHFFFAOYSA-N

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Legal Information

DuPont product

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Statements

H312,H360D

Hazard Classifications

Acute Tox. 4 Dermal - Repr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 1

Flash Point(F)

231.8 °F - closed cup

Flash Point(C)

111 °C - closed cup

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Merwe Albrecht et al.
The journal of physical chemistry. A, 112(33), 7530-7542 (2008-07-31)
Cold, isolated peptide model compounds and their aggregates are generated in pulsed supersonic jet expansions and detected by FTIR spectroscopy in the amide-A region, complemented by amide-I spectra. The most stable, symmetric dimer of formamide is unambiguously assigned in the
João M M Cordeiro et al.
The Journal of chemical physics, 138(4), 044502-044502 (2013-02-08)
The solvation of N-methylformamide (NMF) by dimethylsulfoxide (DMSO) in a 20% NMF/DMSO liquid mixture is investigated using a combination of neutron diffraction augmented with isotopic substitution and Monte Carlo simulations. The aim is to investigate the solute-solvent interactions and the
Shih-Min Wang et al.
The Science of the total environment, 388(1-3), 398-404 (2007-09-15)
N,N-dimethylformamide (DMF) could be readily absorbed via skin and inhalation routes. It is difficult, however, to separate the internal dose contribution from skin vapor and inhalation exposure. This study attempts to quantitatively determine the separate skin vapor and inhalation exposure
Diane Fournier et al.
Applied and environmental microbiology, 75(15), 5088-5093 (2009-06-23)
The propanotroph Rhodococcus ruber ENV425 was observed to rapidly biodegrade N-nitrosodimethylamine (NDMA) after growth on propane, tryptic soy broth, or glucose. The key degradation intermediates were methylamine, nitric oxide, nitrite, nitrate, and formate. Small quantities of formaldehyde and dimethylamine were
Johan Sjödahl et al.
Journal of separation science, 30(1), 104-109 (2007-02-23)
N-Methylformamide (NMF)-based matrices for capillary electrophoretic separation of nucleic acids have been developed. The use of an organic solvent as liquid base for the separation matrices allowed a hydrophobic polymer, C16-derivatized 2-hydroxyethyl cellulose (HEC), to be employed as structural element
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