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M0753

Sigma-Aldrich

Molybdenum(VI) oxide

ReagentPlus®, ≥99.5%

Synonym(s):

Molybdenum trioxide

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About This Item

Linear Formula:
MoO3
CAS Number:
Molecular Weight:
143.94
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:
NACRES:
NA.55

Quality Level

product line

ReagentPlus®

Assay

≥99.5%

form

crystals

reaction suitability

reagent type: catalyst
core: molybdenum

mp

795 °C (lit.)

cation traces

NH4+: ≤0.02%

SMILES string

O=[Mo](=O)=O

InChI

1S/Mo.3O

InChI key

JKQOBWVOAYFWKG-UHFFFAOYSA-N

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Application

Precursor to LAMOX fast ion conductors and superconductors.
Used in the solid state synthesis of a remarkable ternary, reduced molybdenum oxide, Pr4Mo9O18, whose structure contains previously unknown Mo7, Mo13 and Mo19 clusters. The new cluster product is a small band gap semiconductor.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Health hazardExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Kourosh Kalantar-zadeh et al.
Nanoscale, 2(3), 429-433 (2010-07-21)
The formation of MoO(3) sheets of nanoscale thickness is described. They are made from several fundamental sheets of orthorhombic alpha-MoO(3), which can be processed in large quantities via a low cost synthesis route that combines thermal evaporation and mechanical exfoliation.
MoO3 films spin-coated from a nanoparticle suspension for efficient hole-injection in organic electronics.
Jens Meyer et al.
Advanced materials (Deerfield Beach, Fla.), 23(1), 70-73 (2010-10-27)
Lili Cai et al.
Nano letters, 11(2), 872-877 (2011-01-26)
We report an atmospheric, catalyst-free, rapid flame synthesis technique for growing single, branched, and flower-like α-MoO(3) nanobelt arrays on diverse substrates. The growth rate, morphology, and surface coverage density of the α-MoO(3) nanobelts were controlled by varying the flame equivalence
Efficient, large area ITO-and-PEDOT-free organic solar cell sub-modules.
Hui Jin et al.
Advanced materials (Deerfield Beach, Fla.), 24(19), 2572-2577 (2012-04-11)
Jian Liu et al.
Advanced materials (Deerfield Beach, Fla.), 24(20), 2774-2779 (2012-04-19)
High-efficiency inverted polymer solar cells based on PCDTBT:PC(70)BM blend with the MoO(3)-Al composite film as the cathode buffer layer and the MoO(3)/Al as the anode have been demonstrated. A V(OC) of 0.88 V, a J(SC) of 10.88 mA cm(-2), a

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