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31092

Supelco

PCB No 209

analytical standard

Synonym(s):

Decachlorobiphenyl, 2,2′,3,3′,4,4′,5,5′,6,6′-PCB

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About This Item

Empirical Formula (Hill Notation):
C12Cl10
CAS Number:
Molecular Weight:
498.66
Beilstein:
2065289
Ballschmiter Number:
209
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

environmental

format

neat

SMILES string

Clc1c(Cl)c(Cl)c(c(Cl)c1Cl)-c2c(Cl)c(Cl)c(Cl)c(Cl)c2Cl

InChI

1S/C12Cl10/c13-3-1(4(14)8(18)11(21)7(3)17)2-5(15)9(19)12(22)10(20)6(2)16

InChI key

ONXPZLFXDMAPRO-UHFFFAOYSA-N

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General description

PCB No 209 (Decachlorobiphenyl) is a perhalogenated biphenyl pesticide with halogen atoms in ortho-positions. Its phenyl rings have dihedral angle with high rotational barrier around biphenyl linkage.

Application

PCB No 209 has been used as internal standard in gas chromatography (GC-ECD) analysis for determination of deltamethrin.
PCB No 209 may be used as a reference standard for the determination of polychlorinated biphenyls in biota samples and in coastal marine sediments by simultaneous pressurized liquid extraction and purification and gas chromatography with an electron capture detector, respectively.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Pictograms

Health hazardEnvironment

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Target Organs

Endocrine system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

>212.0 °F

Flash Point(C)

> 100.0 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Neustonic versus epiphytic bacteria of eutrophic lake and their biodegradation ability on deltamethrin.
Kalwasinska A
Biodegradation, 22(4), 699-707 (2011)
Decabromobiphenyl (PBB-209) activates the aryl hydrocarbon receptor while decachlorobiphenyl (PCB-209) is inactive: experimental evidence and computational rationalization of the different behavior of some halogenated biphenyls.
Alonso M
Chemical Research in Toxicology, 21(3), 643-658 (2008)
Determination of organochlorine compounds in coastal marine sediments from the southern west of the Mediterranean Sea.
Fouial-Djebbar D, et al.
International Journal of Environmental Science and Technology, 7(2), 271-280 (2010)
Determination of polychlorinated biphenyls in biota samples using simultaneous pressurized liquid extraction and purification.
Gomez-Ariza JL, et al.
Journal of Chromatography A, 946(1-2), 209-219 (2002)
A R Shoaf et al.
Journal of bioluminescence and chemiluminescence, 11(1), 9-22 (1996-01-01)
The reactions between superoxide free radical anion (.O2-) with the halocarbons CCl4. CHCl3, BrCH2CH2Br(EDB), decachlora-biphenyl (DCBP), and 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) in dimethyl sulphoxide (DMSO) results in the emission of chemiluminescence (CL). The chemiluminescence reactions are characterized as having biphasic second order

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