C409

(1R,3S)-(+)-Camphoric acid

99%

• Synonym(s): (+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid
• Empirical Formula (Hill Notation): C₁₀H₁₆O₄
• CAS Number: 124-83-4
• Molecular Weight: 200.23
• UNSPSC Code: 51113400
• NACRES: NA.22
• PubChem Substance ID: 24892576
• EC Number: 204-715-0
• Beilstein/REAXYS Number: 2050204
• MDL number: MFCD00001375
• Assay: 99%
• Form: powder

Properties

• Quality Segment: 200
• assay: 99%
• form: powder
• optical activity: [α]20/D 46°, c = 1 in ethanol
• mp: 183-186 °C (lit.)
• SMILES string: CC1(C)[C@H](CC[C@@]1(C)C(O)=O)C(O)=O
• InChI: 1S/C10H16O4/c1-9(2)6(7(11)12)4-5-10(9,3)8(13)14/h6H,4-5H2,1-3H3,(H,11,12)(H,13,14)/t6-,10+/m1/s1
• InChI key: LSPHULWDVZXLIL-LDWIPMOCSA-N

Description

General description

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

Application

(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H302
• Hazard Classifications: Acute Tox. 4 Oral
• Storage Class: 11 - Combustible Solids
• wgk: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves