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539406

Sigma-Aldrich

Methyl 6-bromo-2-naphthoate

98%

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About This Item

Linear Formula:
BrC10H6CO2CH3
CAS Number:
33626-98-1
Molecular Weight:
265.10
MDL number:
MFCD00100408
UNSPSC Code:
12352100
PubChem Substance ID:
24878396
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

100

Assay

98%

mp

123-126 °C (lit.)

functional group

bromo
ester

SMILES string

COC(=O)c1ccc2cc(Br)ccc2c1

InChI

1S/C12H9BrO2/c1-15-12(14)10-3-2-9-7-11(13)5-4-8(9)6-10/h2-7H,1H3

InChI key

JEUBRLPXJZOGPX-UHFFFAOYSA-N

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General description

Methyl 6-bromo-2-naphthoate undergoes aromatic Finkelstein reaction followed by hydrolysis to afford 6-iodo-2-naphthoic acid.[1]

Application

Methyl 6-bromo-2-naphthoate may be used to synthesize:
  • 6-vinyl-2-naphthalencarbaldehyde[2]
  • methyl 6-(3-tert-butyl-4-methoxyphenyl)-2-naphthoate[3]
  • methyl 6-[3-tert-butyl-4-[(tert-butyldiethylsilyl)oxy]-phenyl]-2-naphthoate[3]
  • methyl 6-[3-(1-adamantyl)-4-[(tert-butyldimethylsilyl)-oxy]phenyl]-2-naphthoate[3]
  • methyl 6-[3-(1-adamantyl)-4-[[(2,3-dimethyl-1,3-dioxolan-4-yl)methylloxy]phenyl]-2-naphthoate[3]
  • 2-bromo-6-(bromomethyl)naphthalene[4]

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCJ8408
MKBN2901V
MKBF2739V
MKBG8988V
MKBF2739

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Carboxy-1, 4-phenylenevinylene-and carboxy-2, 6-naphthylene-vinylene unsymmetrical substituted zinc phthalocyanines for dye-sensitized solar cells.
Silvestri F, et al.
Journal of Porphyrins and Phthalocyanines, 13(03), 369-375 (2009)
B Charpentier et al.
Journal of medicinal chemistry, 38(26), 4993-5006 (1995-12-22)
The retinoic acid receptors (RARs) transduce retinoid dependant gene regulation, and many biological effects of retinoids are mediated through binding and activation of three closely related receptor subtypes (RAR alpha, RAR beta, and RAR gamma). In order to investigate the
Phil M Pithan et al.
Beilstein journal of organic chemistry, 12, 854-862 (2016-06-25)
Cationic biaryl derivatives were synthesized by Suzuki-Miyaura coupling of 3-bromonaphtho[1,2-b]quinolizinium bromide with arylboronic acids. The resulting cationic biaryl derivatives exhibit pronounced fluorosolvatochromic properties. First photophysical studies in different solvents showed that the emission energy of the biaryl derivatives decreases with
Mark W Irvine et al.
Journal of medicinal chemistry, 55(1), 327-341 (2011-11-25)
Competitive N-methyl-d-aspartate receptor (NMDAR) antagonists bind to the GluN2 subunit, of which there are four types (GluN2A-D). We report that some N(1)-substituted derivatives of cis-piperazine-2,3-dicarboxylic acid display improved relative affinity for GluN2C and GluN2D versus GluN2A and GluN2B. These derivatives

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