471984

9-Oxabicyclo[6.1.0]non-4-ene

95%

• Empirical Formula (Hill Notation): C₈H₁₂O
• CAS Number: 637-90-1
• Molecular Weight: 124.18
• EC Number: 211-308-1
• MDL number: MFCD00086420
• UNSPSC Code: 12352100
• PubChem Substance ID: 24870776
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 95%
• refractive index: n20/D 1.495 (lit.)
• bp: 195 °C (lit.)
• density: 1.013 g/mL at 25 °C (lit.)
• SMILES string: C1CC2OC2CCC=C1
• InChI: 1S/C8H12O/c1-2-4-6-8-7(9-8)5-3-1/h1-2,7-8H,3-6H2/b2-1-
• InChI key: YWFPXWMSGJXUFS-UPHRSURJSA-N

Description

General description

9-Oxabicyclo[6.1.0]non-4-ene is an epoxide. It undergoes halofluorination reactions with N-halosuccinimides and triethylamine tris-hydrofluoride or Olah′s reagent.

Application

9-Oxabicyclo[6.1.0]non-4-ene may be used in the following studies:

• novel bicyclo[4.2.1] and bicyclo[3.3.1] ethers
• trans, trans-2,6-dibromo-9-oxabicyclo[3.3.1]nonane and trans, trans-2,5-dibromo-9-oxabicyclo[4.2.1]nonane
• (Z)-2-(cyclooct-4-enyloxy)acetic acid.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): 158.0 °F - closed cup
• Flash Point(C): 70 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves