Chemistry (Weinheim an der Bergstrasse, Germany), 18(46), 14632-14637 (2012-10-16)
Homochiral Dy(III) complexes: by changing the ligand-to-metal ratio, enantiomeric pairs of a Dy(III) complex of different nuclearity could be obtained. The mono- and dinuclear complexes exhibit characteristics of single-molecule magnets and different slow magnetic relaxation processes. In addition, the dinuclear
Dalton transactions (Cambridge, England : 2003), 42(2), 342-346 (2012-11-15)
The heterometallic appended {MMn(III)(4)} (M = Dy(3+) and K(+)) cubanes were firstly trapped by two diamagnetic POM shells, which were robust enough to construct inorganic crystalline tubular materials. Magnetic study reveals the presence of a SMM-like slow magnetic relaxation feature
The first use of N-salicylidene-o-aminophenol in 3d/4f chemistry has led to Mn(III)(4)Dy(III)(5) and Mn(III)(4)Dy(III)(3) clusters with unprecedented metal topologies and stoichiometries; both compounds exhibit out-of-phase signals indicative of the slow magnetization relaxation of a single-molecule magnet.
Chemical communications (Cambridge, England), 48(10), 1508-1510 (2011-09-20)
[Cp(2)Dy(thf)(μ-Cl)](2) (2) was synthesized from [Cp(2)Dy(μ-Cl)](n), which crystalizes as two polymorphs, with n = 2 (1a) or ∞ (1b). All three compounds show slow relaxation of magnetization, and in 2 the quantum tunnelling was found to be exchange-biased.
We report here paramagnetic dysprosium nanomaterial-based T(2) MRI contrast agents. A large r(2) and a negligible r(1) is an ideal condition for T(2) MR imaging. At this condition, protons are strongly and nearly exclusively induced for T(2) MR imaging. The
Rechargeable solid-state batteries are becoming increasingly important due to wide-spread use in computers, portable electronics, and vehicular applications.
Rechargeable solid-state batteries are becoming increasingly important due to wide-spread use in computers, portable electronics, and vehicular applications.
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