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13245

Sigma-Aldrich

Manganese(II) sulfate monohydrate

puriss., meets analytical specification of Ph. Eur, BP, USP, FCC, 99-100.5% (calc. for dried substance)

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About This Item

Linear Formula:
MnSO4 · H2O
CAS Number:
Molecular Weight:
169.02
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21

grade

puriss.

Assay

99-100.5% (calc. for dried substance)

form

powder or crystals

quality

meets analytical specification of Ph. Eur, BP, USP, FCC

impurities

organic volatile impurities, complies (GC)
residual solvents, complies
≤0.002% heavy metals (as Pb)
≤0.5% matter not precip. by ammonia sol.

loss

10-12% loss on ignition, 500 °C

pH

3-3.5 (20 °C, 50 g/L)

anion traces

chloride (Cl-): ≤100 mg/kg

cation traces

As: ≤3 mg/kg
Ca: ≤200 mg/kg
Fe: ≤10 mg/kg
Mg: ≤200 mg/kg
Pb: ≤4 mg/kg
Se: ≤30 mg/kg
Zn: ≤50 mg/kg

suitability

complies for appearance of solution

SMILES string

O.[Mn++].[O-]S([O-])(=O)=O

InChI

1S/Mn.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+2;;/p-2

InChI key

ISPYRSDWRDQNSW-UHFFFAOYSA-L

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General description

Manganese (II) sulfate monohydrate is a safe and inexpensive catalyst used in organic synthesis. Additionally, it is used to prepare manganese dioxide and manganese.

Application

Manganese (II) sulfate monohydrate is used:
  • As a catalyst in the synthesis of heterocyclic compounds such as benzo-2-pyrones and benzopyrazines.
  • To prepare cathode material magnesium manganese spine (MgMn2O4) by coprecipitation method.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 Inhalation

Target Organs

Brain

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Zhehui Weng et al.
Inorganic chemistry, 48(18), 8703-8708 (2009-08-25)
A new glycine-templated manganese(II) sulfate, (C(2)NO(2)H(5))MnSO(4) (1), has been solvothermally synthesized and characterized crystallographically and magnetically. Crystal data for 1: monoclinic, space group P2(1)/m, a = 4.8884(10) A, b = 7.8676(14) A, c = 8.0252(15) A, beta = 106.524(2) degrees
Ramon Frick et al.
Toxicology letters, 205(2), 163-172 (2011-06-15)
Due to their physicochemical characteristics, metal oxide nanoparticles (NPs) interact differently with cells compared to larger particles or soluble metals. Oxidative stress and cellular metal uptake were quantified in rat type II alveolar epithelial cells in culture exposed to three
Stephen F Tomasino et al.
Journal of AOAC International, 90(3), 825-833 (2007-06-22)
AOAC Method 966.04, the Sporicidal Activity of Disinfectants Test, is a carrier-based test that provides a qualitative measure of product efficacy against spores of Bacillus subtilis and Clostridium sporogenes. For regulatory purposes, Method 966.04 is accepted by the U.S. Environmental
A P Marreilha dos Santos et al.
Brain research, 1236, 200-205 (2008-08-30)
Manganese (Mn) is an essential trace element required for ubiquitous enzymatic reactions. Chronic overexposure to this metal may, however, promote potent neurotoxic effects. The mechanism of Mn toxicity is not well established, but several studies indicate that oxidative stress and
Rahim Khabaz
Radiation protection dosimetry, 152(4), 400-405 (2012-05-26)
In this study, an approximate symmetric cylindrical manganese bath system with equal diameter and height was appraised using a Monte Carlo simulation. For nine sizes of the tank filled with MnSO(4).H(2)O solution of three different concentrations, the necessary correction factors

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