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Key Documents

71172

Sigma-Aldrich

Sodium

in kerosene, pieces (large), ≥99.8% (sodium basis)

Synonym(s):

Sodium metal

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About This Item

Empirical Formula (Hill Notation):
Na
CAS Number:
Molecular Weight:
22.99
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

1 mmHg ( 440 °C)

Assay

≥99.8% (sodium basis)

form

pieces (large)

quality

in kerosene

reaction suitability

reagent type: reductant

resistivity

4.69 μΩ-cm, 20°C

bp

883 °C (lit.)

mp

97.8 °C (lit.)

anion traces

chloride, bromide (as Cl)-: ≤20 mg/kg

cation traces

Ca: ≤400 mg/kg
K: ≤300 mg/kg

SMILES string

[Na]

InChI

1S/Na

InChI key

KEAYESYHFKHZAL-UHFFFAOYSA-N

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Application

Sodium metal (in kerosene) has been used in the electrochemical reformation of levulinic acid to form 5-acetyl-2,9-decanedione. It may be used as a drying agent for the purification of tetrahydrofuran (THF).

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Electrochemical synthesis of a novel compound, 5-acetyl-2, 9-decanedione, and theoretical analysis of its lithium ion complex.
Cabasso I
Royal Society of Chemistry Advances, 2(26), 9998-10006 (2012)
Drying of organic solvents: quantitative evaluation of the efficiency of several desiccants.
Williams D
The Journal of Organic Chemistry, 75(24), 8351-8354 (2010)
Highly stable multi-anchored magnetic nanoparticles for optical imaging within biofilms
Stone R C
Journal of Colloid and Interface Science, 459, 175-182 (2015)
Etana Padan
Biochimica et biophysica acta, 1837(7), 1047-1062 (2013-12-24)
The crystal structure of down-regulated NhaA crystallized at acidic pH4 [21] has provided the first structural insights into the antiport mechanism and pH regulation of a Na(+)/H(+) antiporter [22]. On the basis of the NhaA crystal structure [21] and experimental
Martin O'Donnell et al.
The New England journal of medicine, 371(7), 612-623 (2014-08-15)
The optimal range of sodium intake for cardiovascular health is controversial. We obtained morning fasting urine samples from 101,945 persons in 17 countries and estimated 24-hour sodium and potassium excretion (used as a surrogate for intake). We examined the association

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