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578576

Sigma-Aldrich

1,2-Epoxy-3-phenoxypropane

technical grade

Synonym(s):

2,3-Epoxypropyl phenyl ether, Glycidyl phenyl ether, Phenyl glycidyl ether

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About This Item

Empirical Formula (Hill Notation):
C9H10O2
CAS Number:
122-60-1
Molecular Weight:
150.17
Beilstein:
2744
EC Number:
204-557-2
MDL number:
MFCD00005133
UNSPSC Code:
12162002
PubChem Substance ID:
24880937
NACRES:
NA.23

grade

technical grade

vapor density

5.2 (vs air)

vapor pressure

0.03 mmHg ( 20 °C)

refractive index

n20/D 1.53 (lit.)
n20/D 1.530 (lit.)

bp

245 °C (lit.)

mp

3.5 °C (lit.)

density

1.109 g/mL at 25 °C (lit.)

SMILES string

C1OC1COc2ccccc2

InChI

1S/C9H10O2/c1-2-4-8(5-3-1)10-6-9-7-11-9/h1-5,9H,6-7H2

InChI key

FQYUMYWMJTYZTK-UHFFFAOYSA-N

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Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 3 - Carc. 1B - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

237.2 °F - closed cup

Flash Point(C)

114 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Dermatitis from phenyl glycidyl ether.
E Rudzki et al.
Contact dermatitis, 9(1), 90-91 (1983-01-01)
Ida B Niklasson et al.
Chemical research in toxicology, 22(11), 1787-1794 (2009-09-04)
Epoxy resins can be prepared from numerous chemical compositions. Until recently, alternatives to epoxy resins based on diglycidyl ethers of bisphenol A (DGEBA) or bisphenol F (DGEBF) monomers have not received commercial interest, but are presently doing so, as epoxy
Shijin Wu et al.
Applied microbiology and biotechnology, 76(6), 1281-1287 (2007-08-22)
Bacillus sp. Z018, a novel strain producing epoxide hydrolase, was isolated from soil. The epoxide hydrolase catalyzed the stereospecific hydrolysis of (R)-phenyl glycidyl ether to generate (R)-3-phenoxy-1,2-propanediol. Epoxide hydrolase from Bacillus sp. Z018 was inducible, and (R)-phenyl glycidyl ether was
M Garrido et al.
Analytica chimica acta, 585(2), 277-285 (2007-03-28)
This paper reports the validation of the results obtained by combining near infrared spectroscopy and multivariate curve resolution-alternating least squares (MCR-ALS) and using high performance liquid chromatography as a reference method, for the model reaction of phenylglycidylether (PGE) and aniline.
Manfred T Reetz et al.
Organic letters, 6(2), 177-180 (2004-01-16)
[reaction: see text] The epoxide hydrolase (EH) from Aspergillus niger, which shows a selectivity factor of only E = 4.6 in the hydrolytic kinetic resolution of glycidyl phenyl ether, has been subjected to directed evolution for the purpose of enhancing
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