The Palladium particle size is not determined for this product.
674133
Palladium nanoparticles entrapped in aluminum hydroxide matrix
0.5 wt. % loading
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form
solid
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
SMILES string
[Pd].O[Al]=O
InChI
1S/Al.H2O.O.Pd/h;1H2;;/q+1;;;/p-1
InChI key
BBEPUHUDSUQPRM-UHFFFAOYSA-M
General description
A robust palladium heterogenous catalyst.[1]
Application
A recyclable nanocatalyst for the racemization of primary amines. When used in conjunction with a lipase produces enantiopure amines by Dynamic Kinetic Resolution.[2]
Catalyst for:
- Solvent-free hydrogenation
- Aerobic alcohol oxidation
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Min Serk Kwon et al.
Organic letters, 7(6), 1077-1079 (2005-03-12)
[reaction: see text] A new aluminum hydroxide-supported palladium catalyst (1) made by a one-pot synthesis through nanoparticle generation and gelation shows a dual catalytic activity for olefinic hydrogenation and aerobic alcohol oxidation.
Mahn-Joo Kim et al.
Organic letters, 9(6), 1157-1159 (2007-02-13)
A practical procedure for the dynamic kinetic resolution (DKR) of primary amines has been developed. This procedure employs a palladium nanocatalyst as the racemization catalyst, a commercial lipase (Novozym-435) as the resolution catalyst, and ethyl acetate or ethyl methoxyacetate as
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DI CHE DIMENSIONI SONO LE NANOPARTICELLE DI PALLADIO?
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