62421
Lithium aluminum hydride
≥97.0% (gas-volumetric), tablet (5 g each)
Synonym(s):
LAH, Lithium alanate, Lithium tetrahydroaluminate
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About This Item
Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥97.0% (gas-volumetric)
form
tablet (5 g each)
reaction suitability
reagent type: reductant
mp
125 °C (dec.) (lit.)
SMILES string
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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Other Notes
Review[1]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A - Water-react 1
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)
I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
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