377619
D-Threitol
99%
Synonym(s):
(2R,3R)-1,2,3,4-Butanetetrol
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About This Item
Linear Formula:
HOCH2[CH(OH)]2CH2OH
CAS Number:
Molecular Weight:
122.12
Beilstein:
1719752
MDL number:
UNSPSC Code:
12352201
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
solid
optical activity
[α]20/D −14°, c = 2 in ethanol
mp
88-90 °C (lit.)
SMILES string
OC[C@@H](O)[C@H](O)CO
InChI
1S/C4H10O4/c5-1-3(7)4(8)2-6/h3-8H,1-2H2/t3-,4-/m1/s1
InChI key
UNXHWFMMPAWVPI-QWWZWVQMSA-N
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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An enantiospecific synthesis of an orthogonally protected 1,4-trans-1,5-cis-4,5-diamino-2-cyclopenten-1-ol derivative 16 is reported. The trans-diamine moiety was established by anti-specific vinyl addition to a novel threitol-derived tert-butanesulfinylimine 2 and Overman rearrangement. The cyclopentene skeleton was constructed via RCM reaction of a
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