221023
Phenyllithium solution
1.9 M in cyclohexane/ether (7:3)
Synonym(s):
PhLi
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About This Item
Empirical Formula (Hill Notation):
C6H5Li
CAS Number:
Molecular Weight:
84.04
Beilstein:
506502
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
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composition
halide, ~0.05 M
concentration
1.9 M in cyclohexane/ether (7:3)
density
0.828 g/mL at 25 °C
SMILES string
[Li]c1ccccc1
InChI
1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;
InChI key
NHKJPPKXDNZFBJ-UHFFFAOYSA-N
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Packaging
Packaged under nitrogen in poly-coated Sure/Seal™ bottles
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Luka A Wright et al.
Dalton transactions (Cambridge, England : 2003), 44(16), 7230-7241 (2015-03-20)
The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and condensation steps from 6-tributylstannyl-2-(2-methyl-1,3-dioxolan-2-yl)pyridine and 2-bromonitrobenzene. The palladium(II) acetate N,N,N-pincer complexes, [{2-(C6H4-2′-NH)-6-(CMe=NAr)C5H3N}Pd(OAc)] (Ar = 4-i-PrC6H4 (1a), 2,6-i-Pr2C6H3 (1b)), can be prepared by
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