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Sigma-Aldrich

Poly(methyl methacrylate)

average Mw ~15,000 by GPC, powder

Synonym(s):

PMMA, Poly(methacrylic acid methyl ester)

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About This Item

Linear Formula:
[CH2C(CH3)(CO2CH3)]n
CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

powder

Quality Level

autoignition temp.

580 °F

mol wt

average Mw ~15,000 by GPC

transition temp

Tg (DSC) 105 °C (midpoint)

solubility

dichloromethane: 25 mg/mL, clear to hazy

density

1.200 g/cm3

InChI

1S/C5H9O2/c1-4(2)5(6)7-3/h1-3H3

InChI key

PMAMJWJDBDSDHV-UHFFFAOYSA-N

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General description

Poly (methyl methacrylate) (PMMA) is an amorphous transparent thermoplastic polymer. PMMA is recognized as an optical polymer based on its refractive index (1.49). Hence, it is used in optical fibers. It finds uses in biological applications because of its lower water absorption capability and biocompatibility. The maximum moisture content of PMMA is 1.71% and SBF absorption is 1.96%. Simulated Body fluid test (SBF) is a method to identify the in vitro bioactivity of ceramic materials, by immersing the materials in an aqueous SBF solution.

Application

PMMA may be used as substrate for graphene growth. Some studies report its use as
  • PMMA-titania hybrid optical thins films
  • PMMA/polystryrene/clay nanocomposites
  • PMMA/polyurethane/carbon black nanocomposites for methanol fuel cells
  • acrylic glass
  • implant in surgical specialties
  • as spacer.

Storage Class Code

11 - Combustible Solids

WGK

nwg

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Mechanical and Tribological Properties of PMMA-Sea Shell based Biocomposite for Dental application.
Kartick R, et al.
Procedia Materials Science, 6, 1989-2000 (2014)
Bon Min Koo et al.
Scientific reports, 9(1), 9755-9755 (2019-07-07)
A synaptic device that functionally mimics a biological synapse is a promising candidate for use as an electronic element in a neuromorphic system. In this study, flexible electronic synaptic devices based on poly (methyl methacrylate) (PMMA):CdSe/CdZnS core-shell quantum-dot (QD) nanocomposites
Transparent conductive electrodes."
Yu K and Chen J
Material Matters, 9(1), 6-6 null
High-refractive-index thin films prepared from trialkoxysilane-capped poly (methyl methacrylate)-titania materials
Lee LH and Chen WC
Chemistry of Materials, 13(3), 1137-1142 null
Synthesis of Ethylene Glycol Dimethacrylate-Methyl Methacrylate Copolymers, Determination of their Reactivity Ratios, and a Study of Dopant and Temperature Effects on their Conductivities
Ramelow US and Pingili S
Polymer, 2(3), 265-285 (2010)

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