Chemistry (Weinheim an der Bergstrasse, Germany), 17(31), 8671-8695 (2011-06-21)
Crystal structures of two metal-organic frameworks (MFU-1 and MFU-2) are presented, both of which contain redox-active Co(II) centres coordinated by linear 1,4-bis[(3,5-dimethyl)pyrazol-4-yl] ligands. In contrast to many MOFs reported previously, these compounds show excellent stability against hydrolytic decomposition. Catalytic turnover
Journal of the American Chemical Society, 126(34), 10542-10543 (2004-08-26)
Hydrocarbon oxyfunctionalization is a crucial industrial process. Most metallic catalysts require higher temperatures and often show lower selectivities. One of the intellectual approaches is the mimicry for bio-oxidation. We have established a biomimetic system with a nonmetallic redox center, composed
The Journal of organic chemistry, 77(22), 9959-9969 (2012-11-02)
A direct conversion of C(sp(3))-H bonds to C(sp(3))-N bonds has been achieved by utilizing catalytic N-hydroxyphthalimide (NHPI) and stoichiometric dialkyl azodicarboxylate. NHPI functions as a precursor of the electron-deficient phthalimide N-oxyl radical (PINO) to abstract hydrogens, and dialkyl azodicarboxylate acts
Application of a dual linker with a reference cleavage site to discover a new reaction between amines and N-hydroxyphthalimide.
Viktor Krchnák et al.
Journal of combinatorial chemistry, 7(4), 523-525 (2005-07-12)
European journal of biochemistry, 269(21), 5330-5335 (2002-10-24)
To investigate how solubility and steric issues affect the laccase-catalysed oxidation of phenols, a series of oligomeric polyphenol compounds, having increasing size and decreasing solubility in water, was incubated with laccase. The extent of substrate conversion, and the nature of
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