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D176605

Sigma-Aldrich

4,5-Dimethyl-1,2-phenylenediamine

98%

Synonym(s):

4,5-Diamino-o-xylene

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About This Item

Linear Formula:
(CH3)2C6H2(NH2)2
CAS Number:
Molecular Weight:
136.19
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

powder

mp

127-129 °C (lit.)

storage temp.

2-8°C

SMILES string

Cc1cc(N)c(N)cc1C

InChI

1S/C8H12N2/c1-5-3-7(9)8(10)4-6(5)2/h3-4H,9-10H2,1-2H3

InChI key

XSZYBMMYQCYIPC-UHFFFAOYSA-N

Related Categories

Application

Employed in the preparation of transition metal complexes and quinoxalinones.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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K Mori et al.
Chemical & pharmaceutical bulletin, 46(9), 1474-1476 (1998-10-17)
A simple and accurate method for determination of vitamin C (ascorbic acid (AsA) and dehydroascorbic acid (DHA)) using 4,5-dimethyl-o-phenylenediamine (DMPD) was investigated. It was found that DMPD is a useful fluorescent reagent. The reaction product of DMPD with DHA showed
Bull. Korean Chem. Soc., 15, 1122-1122 (1994)
M Katayama et al.
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 110(10), 776-782 (1990-10-01)
Twelve purines oxidized with 4,5-dimethyl-o-phenylenediamine (DMPD) was found to react with N-bromosuccinimide (NBS) to give fluorescent derivatives. In this paper, the identification of oxidation and fluorescent products have been described. In compliance with the substituent on purine skelton, three alloxans
A Bishop et al.
Free radical biology & medicine, 17(4), 311-320 (1994-10-01)
PQQ, also called methoxatin, has been isolated from guinea-pig neutrophils. The organic cations diphenyleneiodonium (DPI) and diphenyliodonium (BPI) and the aromatic o-diamine 4,5-dimethylphenylenediamine (DIMPDA) sequester synthetic PQQ and inhibit its redox-cycling activity in a model system. Standards were made of
Sarah J M Zaytsoff et al.
Gut pathogens, 12, 24-24 (2020-05-12)
This study utilized a chicken model of chronic physiological stress mediated by corticosterone (CORT) administration to ascertain how various host metrics are altered upon challenge with Clostridium perfringens. Necrotic enteritis (NE) is a disease of the small intestine of chickens

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