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935999

Sigma-Aldrich

Sodium triflate solution

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greener alternative

in Bis(2-methoxyethyl) ether, 1.0 M NaTfO in diglyme, battery grade

Synonym(s):

1.0 M NaTfO in diglyme

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About This Item

UNSPSC Code:
12352600

grade

battery grade

Quality Level

100

form

solution

greener alternative product characteristics

Design for Energy Efficiency
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concentration

0.95-1.10 M (NaPF6)

impurities

≤100 ppm H2O

anion traces

chloride (Cl-): ≤200 ppm
sulfate (SO42-): ≤200 ppm

application(s)

battery manufacturing

greener alternative category

Enabling

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General description

Our battery grade sodium triflate solution in bis(2-methoxyethyl) ether (diglyme) is a clear solution containing 1.0 M sodium triflate dissolved in diglyme. To perform optimally in battery applications, we strictly minimize impurities including low moisture, low trace metals, low chloride, and low sulfate.
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Application

Our 1.0 M NaTfO in diglyme, battery grade is an electrolyte designed for use in sodium-ion batteries (SIBs) and sodium superoxide (NaO2) batteries.[1,2] Studies have found that diglyme-based electrolytes can be used in sodium-ion batteries with graphite anode by overcoming the lack of suitable binary intercalation compounds in Na-C system.[3] Ether based electrolytes have the ability to trigger the highly reversible co-intercalation of sodium ions with an ether solvent into graphite, and form a stable solid electrolyte interphase (SEI).[4]

Signal Word

Danger

Hazard Statements

H226,H315,H319,H360FD

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

134.6 °F

Flash Point(C)

57 °C

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Pascal Hartmann et al.
Physical chemistry chemical physics : PCCP, 15(28), 11661-11672 (2013-04-05)
This work reports on the cell chemistry of a room temperature sodium-oxygen battery using an electrolyte of diethylene glycol dimethyl ether (diglyme) and sodium trifluoromethanesulfonate (NaSO3CF3, sodium triflate). Different from lithium-oxygen cells, where lithium peroxide is found as the discharge
Electrolytes and Interphases in Sodium-Based Rechargeable Batteries: Recent Advances and Perspectives
Eshetu, Gebrekidan Gebresilassie, et al.
Advanced Energy Materials, 10 (2020)
Kaikai Li et al.
Nature communications, 10(1), 725-725 (2019-02-15)
Ether based electrolytes have surfaced as alternatives to conventional carbonates allowing for enhanced electrochemical performance of sodium-ion batteries; however, the primary source of the improvement remains poorly understood. Here we show that coupling titanium dioxide and other anode materials with
Birte Jache et al.
Angewandte Chemie (International ed. in English), 53(38), 10169-10173 (2014-07-25)
Although being the standard anode material in lithium-ion batteries (LIBs), graphite so far is considered to fail application in sodium-ion batteries (NIBs) because the Na-C system lacks suitable binary intercalation compounds. Here we show that this limitation can be circumvented

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