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Sigma-Aldrich

1,3,5-Tris(4-bromophenyl)benzene

97%

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About This Item

Empirical Formula (Hill Notation):
C24H15Br3
CAS Number:
Molecular Weight:
543.09
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Assay

97%

form

solid

mp

261-265 °C

SMILES string

Brc1ccc(cc1)-c2cc(cc(c2)-c3ccc(Br)cc3)-c4ccc(Br)cc4

InChI

1S/C24H15Br3/c25-22-7-1-16(2-8-22)19-13-20(17-3-9-23(26)10-4-17)15-21(14-19)18-5-11-24(27)12-6-18/h1-15H

InChI key

HJQRITCAXSBOPC-UHFFFAOYSA-N

General description

1,3,5-Tris(4-bromophenyl)benzene (TBB) is a halogenated aromatic monomer that can be used in the formation of covalent aromatic frameworks(COF).

Application

TBB can be used to synthesize porous aromatic frameworks for the development of adsorption membranes to treat organic pollutants. It can also be used in the fabrication of pyridine based high efficiency organic light emitting diodes(OLEDs).

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Aquatic Chronic 4 - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Star-shaped oligothiophenes for solution-processible organic electronics: flexible aliphatic spacers approach
Ponomarenko SA, et al.
Chemistry of Materials, 18(17), 4101-4108 (2006)
Surface mediated synthesis of 2D covalent organic frameworks: 1, 3, 5-tris (4-bromophenyl) benzene on graphite (001), Cu (111), and Ag (110)
Gutzler R, et al.
Chemical Communications (Cambridge, England), 4456-4458 (2009)
Synthesis of a porous aromatic framework for adsorbing organic pollutants application
Ren H, et al.
Journal of Materials Chemistry, 21(28), 10348-10353 (2011)
Pyridine-containing triphenylbenzene derivatives with high electron mobility for highly efficient phosphorescent OLEDs
Su, Shi-Jian; Chiba, Takayuki; et al.
Advanced Materials, 20(11), 2125-2130 (2008)
Ruiyan Sun et al.
ChemSusChem, 12(14), 3278-3285 (2019-04-30)
Methyl formate was produced in one pot through the hydrogenation of CO2 to formic acid/formate followed by an esterification step. The route offers the possibility to integrate renewable energy into the fossil-based chemical value chain. In this work, a phosphine-polymer-anchored

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