590231

Di(acetato)dicyclohexylphenylphosphinepalladium(II), polymer-bound FibreCat^®

Pd ~5 %, extent of labeling: 0.4-0.6 mmol/g PPH₃ ligand content loading

• CAS Number: 480445-43-0
• MDL number: MFCD04118909
• UNSPSC Code: 12352103
• NACRES: NA.22

Properties

• product line: FibreCat^®
• form: solid
• composition: Pd, ~5%
• reaction suitability: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reaction type: solution phase peptide synthesis; reagent type: catalyst; reaction type: Coupling Reactions
• extent of labeling: 0.4-0.6 mmol/g PPH₃ ligand content loading

Description

Application

Supported catalyst used in Suzuki coupling of less reactive aryl chloride with boronic acids. This supported catalyst is generally more selective than the free homogeneous catalyst, and palladium leaching is very low (<2 ppm).

The resin can also be recycled.

Legal Information

FibreCat is a registered trademark of Johnson Matthey PLC

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves