Skip to Content
Merck
All Photos(2)

Documents

425710

Sigma-Aldrich

Samarium(III) trifluoromethanesulfonate

98%

Synonym(s):

Samarium(III) triflate, Trifluoromethanesulfonic acid samarium(III) salt

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
Sm(SO3CF3)3
CAS Number:
52093-28-4
Molecular Weight:
597.57
MDL number:
MFCD00192431
UNSPSC Code:
12161600
PubChem Substance ID:
24866661
NACRES:
NA.22

Assay

98%

reaction suitability

core: samarium
reagent type: catalyst

SMILES string

[Sm+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/3CHF3O3S.Sm/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3

InChI key

DDCWGUIPLGMBPO-UHFFFAOYSA-K

Looking for similar products? Visit Product Comparison Guide

Application

A water-tolerant Lewis acid used in the Aldol reaction of silyl enol ethers with aldehydes.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

The Journal of Organic Chemistry, 59, 3590-3590 (1994)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service