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362212

Sigma-Aldrich

Iododioxobis(triphenylphosphine)rhenium(V)

98%

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About This Item

Linear Formula:
[(C6H5)3P]2ReO2I
CAS Number:
23032-93-1
Molecular Weight:
869.68
MDL number:
MFCD00151571
UNSPSC Code:
12352300
PubChem Substance ID:
24862298
NACRES:
NA.22

Assay

98%

form

solid

reaction suitability

core: rhenium
reagent type: catalyst

mp

195-197 °C (lit.)

SMILES string

I[Re](=O)=O.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6

InChI

1S/2C18H15P.HI.2O.Re/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;/h2*1-15H;1H;;;/q;;;;;+1/p-1

InChI key

PMWGPGWRMJAPNT-UHFFFAOYSA-M

Application

Catalyst for:
  • Chemoselective direct reductive amination reactions
  • Selective hydrogenation reactions
  • Living radical polymerization reactions

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBV0972V
MKBQ1577V
MKBG5827V
02918ME
11526MW

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