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341630

Sigma-Aldrich

Chloro(pyridine)bis(dimethylglyoximato)cobalt(III)

Synonym(s):

Chloro(pyridine)cobaloxime(III), NSC 175756

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About This Item

Empirical Formula (Hill Notation):
C13H19ClCoN5O4
CAS Number:
23295-32-1
Molecular Weight:
403.71
MDL number:
MFCD00075236
UNSPSC Code:
12161600
PubChem Substance ID:
24860975
NACRES:
NA.22

reaction suitability

core: cobalt
reaction type: Photocatalysis
reagent type: catalyst

mp

235 °C (dec.) (lit.)

SMILES string

c1ccncc1.CC(=N\O)\C(C)=N/O[Co](Cl)O\N=C(C)/C(C)=N\O

InChI

1S/C5H5N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H;2*7-8H,1-2H3;1H;/q;;;;+3/p-3/b;2*5-3-,6-4-;;

InChI key

CKWAWSVVCRVWHW-PCJYWUFNSA-K

Related Categories

Application

Catalyst for:
  • Photocatalytic H2 generation from water under visible light
  • Doetz benzannulation reaction
  • Proton electroreduction reactions
  • Radical heterocyclization reactions
  • Preparation of Mannich base analogues
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Agnès Barbance et al.
Frontiers in microbiology, 11, 590061-590061 (2020-11-27)
Chlordecone (Kepone®) and γ-hexachlorocyclohexane (γ-HCH or lindane) have been used for decades in the French West Indies (FWI) resulting in long-term soil and water pollution. In a previous work, we have identified a new Citrobacter species (sp.86) that is able

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