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About This Item
Linear Formula:
(CH3O)2C6H3CHO
CAS Number:
Molecular Weight:
166.17
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
99%
form
solid
bp
285 °C (lit.)
mp
96-98 °C (lit.)
SMILES string
COc1cccc(OC)c1C=O
InChI
1S/C9H10O3/c1-11-8-4-3-5-9(12-2)7(8)6-10/h3-6H,1-2H3
InChI key
WXSGQHKHUYTJNB-UHFFFAOYSA-N
General description
Demethylation of 2,6-dimethoxybenzaldehydes with magnesium iodide etherate has been studied.
Application
2,6-Dimethoxybenzaldehyde has been used in the preparation of 2,6-dihydroxybenzaldehyde by demethylation with AlBr3.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Regioselective demethylation of 2, 6-dimethoxybenzaldehydes with magnesium iodide etherate.
Yamaguchi S, et al.
Tetrahedron Letters, 40(41), 7363-7365 (1999)
Synthesis of facially-encumbered porphyrins. An approach to light-harvesting antenna complexes.
Wagner RW, et al.
Tetrahedron Letters, 32(14), 1703-1706 (1991)
Olga V Kupriyanova et al.
Drug testing and analysis, 12(8), 1154-1170 (2020-05-18)
N-(2-Methoxybenzyl)-2,5-dimethoxyphenethylamines (NBOMes) are synthetic phenethylamine derivatives emerging on the global drug market and reported to be associated with untoward effects in people who use drugs. Its action involves agonism at serotonin 5-HT2A receptors, affecting cognitive and behavioral processes. However, certain
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