275131

Bis(1,5-cyclooctadiene)diiridium(I) dichloride

97%

• Synonym(s): [Ir(1,5-cod)Cl]2, 1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer, Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium, Iridium(I) chloride 1,5-cyclooctadiene complex dimer, [Ir(1,5-cod)Cl]₂, [Ir(cod)Cl]2
• Empirical Formula (Hill Notation): C₁₆H₂₄Cl₂Ir₂
• CAS Number: 12112-67-3
• Molecular Weight: 671.70
• EC Number: 235-170-7
• MDL number: MFCD00012414
• UNSPSC Code: 12352300
• PubChem Substance ID: 24856629

Properties

• Assay: 97%
• reaction suitability: reagent type: catalyst; core: iridium
• mp: 205 °C (dec.) (lit.)
• SMILES string: Cl[Ir].Cl[Ir].C1CC=CCCC=C1.C2CC=CCCC=C2
• InChI: 1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2/b2*2-1-,8-7-;;;;
• InChI key: ZFOUDQNHNLDNLD-MIXQCLKLSA-L

Description

Application

Metal precursor for asymmetric allylic substitutions.