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Key Documents

261262

Sigma-Aldrich

Scandium

powder, 99.9% trace rare earth metals basis

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About This Item

Empirical Formula (Hill Notation):
Sc
CAS Number:
Molecular Weight:
44.96
EC Number:
MDL number:
UNSPSC Code:
12141613
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

99.9% trace rare earth metals basis

form

powder

resistivity

50.5 μΩ-cm, 0°C

bp

2836 °C (lit.)

mp

1540 °C (lit.)

density

2.99 g/mL at 25 °C (lit.)

SMILES string

[Sc]

InChI

1S/Sc

InChI key

SIXSYDAISGFNSX-UHFFFAOYSA-N

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Application

Employed in solid state synthesis of unusual clusters, Sc19Br28Z4, (Z=Mn, Fe, Ru or Os). These clusters are of interest for their structure and magnetic properties.

Pictograms

Flame

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Andrea Olmos et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(16), 4894-4901 (2012-03-15)
This study demonstrates the first zeolite-catalyzed synthesis of piperidine derivatives, including peptidomimetics and indoloquinolizidine alkaloids. The approach developed utilizes a highly effective one-pot reaction cascade, through imine formation and imino-Diels-Alder reactions, promoted by scandium-loaded zeolites as a heterogeneous catalyst. The
Jacob S Kanady et al.
Journal of the American Chemical Society, 135(3), 1073-1082 (2012-12-18)
The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable
Asymmetric synthesis of β-amino nitriles through a Sc(III)-catalyzed three-component Mannich reaction of silyl ketene imines.
Jiannan Zhao et al.
Angewandte Chemie (International ed. in English), 52(12), 3473-3477 (2013-02-14)
E Koumarianou et al.
Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine, 70(12), 2669-2676 (2012-10-06)
In the present study we demonstrate the in vitro and in vivo comparison of the (44)Sc and (68)Ga labeled DOTA-BN[2-14]NH(2). (44)Sc is a positron emitter with a half life of 3.92 h. Hence it could be used for PET imaging
Xiuzhen Yu et al.
Proceedings of the National Academy of Sciences of the United States of America, 109(23), 8856-8860 (2012-05-23)
It was recently realized that topological spin textures do not merely have mathematical beauty but can also give rise to unique functionalities of magnetic materials. An example is the skyrmion--a nano-sized bundle of noncoplanar spins--that by virtue of its nontrivial

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