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250171

Sigma-Aldrich

Sodium hexafluorosilicate

Synonym(s):

Disodium hexafluorosilicon(2-), Sodium fluosilicate

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About This Item

Linear Formula:
Na2SiF6
CAS Number:
16893-85-9
Molecular Weight:
188.06
EC Number:
240-934-8
MDL number:
MFCD00003491
UNSPSC Code:
12352302
PubChem Substance ID:
24855039
NACRES:
NA.23

form

powder

density

2.68 g/mL at 25 °C (lit.)

SMILES string

[Na+].[Na+].F[Si--](F)(F)(F)(F)F

InChI

1S/F6Si.2Na/c1-7(2,3,4,5)6;;/q-2;2*+1

InChI key

TWGUZEUZLCYTCG-UHFFFAOYSA-N

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Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H301 + H311 + H331

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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[Recurrent ventricular fibrillation in magnesium fluosilicate poisoning].
B Suberviola Cañas et al.
Medicina intensiva, 31(6), 344-346 (2007-08-01)
Toshiyuki Suge et al.
American journal of dentistry, 19(4), 248-252 (2006-08-31)
To evaluate the occluding ability of ammonium hexafluorosilicate (SiF). Dentin disks prepared from human extracted teeth were grouped as follows to prepare different situations of dentin hypersensitivity: (1) those sonicated for 20 minutes; (2) those treated with 0.5 mol/L EDTA
Toshiyuki Suge et al.
Dental materials : official publication of the Academy of Dental Materials, 24(2), 192-198 (2007-06-05)
Diamine silver fluoride [AgF: (NH(3))(2)AgF] has been used clinically in Japan, as it reduces dental caries and dentin hypersensitivity. However, AgF stains the teeth black due to silver precipitation. To overcome this drawback, the authors prepared ammonium hexafluorosilicate [SiF: (NH(4))(2)SiF(6)]
Teresa Lech
Forensic science international, 206(1-3), e20-e24 (2010-07-27)
Fluoride, of all inorganic substances, is among the least likely to be identified by a routine toxicological analysis. Acute poisonings with salts of hydrofluoric or fluorosilicic acid, however, although relatively uncommon, may occur. Some fluorosilicates, salts of fluorosilicic acid (e.g.
Shingo Shibata et al.
American journal of dentistry, 25(1), 31-34 (2012-05-09)
This study evaluated the antibacterial activity of the SiF solution with the addition of antibacterial agents on a Streptococcus mutans biofilm. Various antibacterial SiF solutions were prepared by adding chlorhexidine, cetylpyridinium chloride, isopropyl methylphenol, or epigallocatechin gallate. Hydroxyapatite pellets treated
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