178721

(Diacetoxyiodo)benzene

98%

• Synonym(s): Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate
• Linear Formula: C₆H₅I(O₂CCH₃)₂
• CAS Number: 3240-34-4
• Molecular Weight: 322.10
• Beilstein: 1879369
• EC Number: 221-808-1
• MDL number: MFCD00008692
• UNSPSC Code: 12352002
• PubChem Substance ID: 24850764
• NACRES: NA.22

Properties

• Assay: 98%
• form: powder
• reaction suitability: reagent type: catalyst; reagent type: oxidant; reaction type: C-H Activation
• mp: 161-163 °C (lit.)
• SMILES string: CC(OI(OC(C)=O)C1=CC=CC=C1)=O
• InChI: 1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
• InChI key: ZBIKORITPGTTGI-UHFFFAOYSA-N

Description

Application

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Stoichiometric oxidant in the TEMPO oxidation of nerol to neral. Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.

Unactivated sp³ C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)₂ as a stoichiometric oxidant.

Used in the room temperature Pd-catalyzed 2-arylation of indoles

Useful reagent for the synthesis of a wide variety of heterocyclic compounds.

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves