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O9409

Sigma-Aldrich

2-Oxazolidinone

98%

Synonym(s):

1,3-Oxazolidin-2-one, 2-Oxazolidone, 2-Oxo-1,3-oxazolidine, 2-Oxotetrahydro-1,3-oxazole

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About This Item

Empirical Formula (Hill Notation):
C3H5NO2
CAS Number:
497-25-6
Molecular Weight:
87.08
Beilstein:
106251
EC Number:
207-840-9
MDL number:
MFCD00005268
UNSPSC Code:
12352100
PubChem Substance ID:
24898070
NACRES:
NA.22

Assay

98%

form

solid

bp

220 °C/48 mmHg (lit.)

mp

83-87 °C (lit.)

SMILES string

O=C1NCCO1

InChI

1S/C3H5NO2/c5-3-4-1-2-6-3/h1-2H2,(H,4,5)

InChI key

IZXIZTKNFFYFOF-UHFFFAOYSA-N

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Application

2-Oxazolidinone can be employed as a precursor for the preparation of acryloyloxazolidin-2-ones , trans-3-cinnamoyloxazolidin-2-one, 3-bromo-2-oxazolidinone , 4-methoxy-2-oxazolidinone , coordination compound, tetrakis[μ-(2-oxazolidinonato-κN3:κO2)]tetra-, (4Cu-Cu).

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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A number of cyclic derivatives of 3-amino-2,4-dihydroxybutanoic acid are known in the literature but they are often prepared from other cyclic precursors. This study showed that the title compound too may serve as a convenient substrate for cyclization reactions. Using
Cysteine-Aminoethylation-Assisted Chemical Ubiquitination of Recombinant Histones
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Journal of the American Chemical Society, 141(8), 3654-3663 (2019)
Asymmetric Diels-Alder Reaction of α,β -Unsaturated Oxazolidin-2-one Derivatives Catalyzed by a Chiral Fe (III)-Bipyridine Diol Complex
Li Mao, et al.
Organic Letters, 20(4), 995-998 (2018)
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