562629

Nonafluorobutane-1-sulfonic acid

97%

• Synonym(s): 1,1,2,2,3,3,4,4,4-Nonafluoro-1-butanesulfonic acid, 1-Perfluorobutanesulfonic acid, Nonafluoro-1-butanesulfonic acid, Nonafluorobutan-1-sulfonic acid, Nonafluorobutanesulfonic acid, Perfluorobutanesulfonic acid, n-Nonafluorobutanesulfonic acid
• Linear Formula: CF₃(CF₂)₃SO₃H
• CAS Number: 375-73-5
• Molecular Weight: 300.10
• EC Number: 206-793-1
• MDL number: MFCD01320794
• UNSPSC Code: 12352100
• PubChem Substance ID: 24880050
• NACRES: NA.22

Properties

• Assay: 97%
• refractive index: n20/D 1.3230 (lit.)
• bp: 112-114 °C/14 mmHg (lit.)
• density: 1.811 g/mL at 25 °C (lit.)
• functional group: fluoro; sulfonic acid
• storage temp.: 2-8°C
• SMILES string: OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
• InChI: 1S/C4HF9O3S/c5-1(6,3(9,10)11)2(7,8)4(12,13)17(14,15)16/h(H,14,15,16)
• InChI key: JGTNAGYHADQMCM-UHFFFAOYSA-N

Description

General description

Nonafluorobutane-1-sulfonic acid is a colorless liquid that can be considered as a superacid, which can be synthesized by reacting 1-iodononafluorobutane with sodium dithionite in the presence of sodium bicarbonate in acetonitrile/water.

Application

Nonafluorobutane-1-sulfonic acid may be used as catalyst in the synthesis of 6-chloro-6H-dibenz[c,e][1,2]oxaphosphorin and N-benzylpyridin-2-amine.

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302,H314
• Precautionary Statements: P270 - P280 - P301 + P312 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B
• Supplementary Hazards: EUH014
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): 350.6 °F - Pensky-Martens closed cup
• Flash Point(C): 177 °C - Pensky-Martens closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves