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Key Documents

269158

Sigma-Aldrich

(Bromomethyl)triphenylphosphonium bromide

98%

Synonym(s):

NSC 193751

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About This Item

Linear Formula:
BrCH2P(Br)(C6H5)3
CAS Number:
Molecular Weight:
436.12
Beilstein:
3579901
EC Number:
MDL number:
UNSPSC Code:
12352002
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

98%

form

solid

reaction suitability

reaction type: C-C Bond Formation

mp

234-236 °C (lit.)

SMILES string

[Br-].BrC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C19H17BrP.BrH/c20-16-21(17-10-4-1-5-11-17,18-12-6-2-7-13-18)19-14-8-3-9-15-19;/h1-15H,16H2;1H/q+1;/p-1

InChI key

YFTMLUSIDVFTKU-UHFFFAOYSA-M

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Application

Reactant or reagent for synthesis of:
  • Vernonia allenes and sesquiterpenoids
  • Monohalovinylated pyrethoids with insecticidal activity
  • Vitamin D analogs with anticancer activity

Reactant for:
  • Asymmetric substitution affecting optical properties of boradiazaindacene dyes
  • Carbanionic rearrangements of halomethylenecyclobutanes

Used for diferrocenyl molecular wires

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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