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234958

Sigma-Aldrich

1,4-Butanediol dimethacrylate

95%, contains 200-300 ppm MEHQ as inhibitor

Synonym(s):

BDDMA, Butanediol dimethacrylate, Tetramethylene methacrylate

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About This Item

Linear Formula:
[H2C=C(CH3)CO2CH2CH2-]2
CAS Number:
Molecular Weight:
226.27
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

95%

form

liquid

contains

200-300 ppm MEHQ as inhibitor

refractive index

n20/D 1.456 (lit.)

bp

132-134 °C/4 mmHg (lit.)

density

1.023 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OCCCCOC(=O)C(C)=C

InChI

1S/C12H18O4/c1-9(2)11(13)15-7-5-6-8-16-12(14)10(3)4/h1,3,5-8H2,2,4H3

InChI key

XOJWAAUYNWGQAU-UHFFFAOYSA-N

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Application

  • Formulation and polymerization of foamed 1,4-BDDMA-in-water emulsions.: This study focuses on the formulation and polymerization processes of 1,4-Butanediol dimethacrylate (1,4-BDDMA) in water emulsions, showcasing its potential in creating high-performance polymer foams suitable for various industrial applications (Dabrowski et al., 2020).
  • Methacrylate-based polymer foams with controllable connectivity, pore shape, pore size and polydispersity.: The research delves into creating methacrylate-based polymer foams using 1,4-BDDMA, emphasizing its versatility in producing materials with tailored physical properties, which are crucial for biomedical and industrial uses (Dabrowski et al., 2019).
  • Double Replication of Silica Colloidal Crystal Films.: This paper discusses the replication of silica colloidal crystal films using 1,4-BDDMA, highlighting its efficacy in creating structured materials for advanced technological applications (Russell and Mallouk, 2017).
  • In-situ photocrosslinkable nanohybrid elastomer based on polybutadiene/polyhedral oligomeric silsesquioxane.: This study investigates the development of a nanohybrid elastomer using 1,4-BDDMA, focusing on its applications in medical device adhesives and high-performance polymer synthesis (Mirmohammadi et al., 2016).
  • Effects of dental methacrylates on oxygen consumption and redox status of human pulp cells.: Research highlighting the biocompatibility and potential dental applications of 1,4-BDDMA, demonstrating its impact on human pulp cells, which is critical for dental composite materials (Nocca et al., 2014).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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M Krishna Kumar et al.
Journal of peptide science : an official publication of the European Peptide Society, 8(5), 183-191 (2002-06-05)
A highly solvating copolymer was prepared in high yield by introducing a flexible crosslinker, 1,4-butanedioldimethacrylate, into the polystyrene matrix by a free radical aqueous suspension polymerization. A 2 mol% crosslinked resin showed rigidity and mechanical characteristics comparable to those of
Susanna Segerström et al.
European journal of oral sciences, 119(3), 246-252 (2011-05-14)
The aim of this study was to determine water sorption, water solubility, dimensional change caused by water storage, residual monomers, and possible cytotoxic effects of heat-polymerized carbon-graphite fibre-reinforced composites with different fibre loadings based on methyl methacrylate/poly(methyl methacrylate) (MMA/PMMA) and
Susanna Segerström et al.
European journal of oral sciences, 113(5), 422-428 (2005-10-06)
Two matrix resins for fiber composites that remain in a fluid state during storage and handling before polymerization were evaluated. The resin mixtures, based on methyl methacrylate (MMA), were produced with two different cross-linking agent systems: 1,4-butanediol dimethacrylate and ethylene
Aude Heloise Bonardi et al.
Macromolecular rapid communications, 40(23), e1900495-e1900495 (2019-10-31)
Photo-induced thermal polymerization upon near-infrared (NIR) light irradiation has been reported in the literature. In this approach, a component able to convert the NIR light into heat must be used in combination with a thermal initiator to initiate the free-radical
Eeva K Viljanen et al.
Dental materials : official publication of the Academy of Dental Materials, 22(9), 845-851 (2005-12-29)
The aim of this study was to analyze the residual monomer content of photopolymerized dendritic methacrylate copolymers and particulate filler composites. Headspace-gas chromatography/mass spectrometry (HS-GC/MS) was compared with high performance liquid chromatography (HPLC). The resin mixtures consisted of a dendritic

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