57457
1-Butyl-3-methylimidazolium hydrogen sulfate
≥95% (HPLC)
Synonym(s):
[BMIM][HSO4]
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About This Item
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Quality Level
Assay
≥95% (HPLC)
greener alternative product characteristics
Safer Solvents and Auxiliaries
Catalysis
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impurities
≤1.0% water
anion traces
chloride (Cl-): ≤1%
greener alternative category
, Aligned
SMILES string
OS([O-])(=O)=O.CCCCn1cc[n+](C)c1
InChI
1S/C8H15N2.H2O4S/c1-3-4-5-10-7-6-9(2)8-10;1-5(2,3)4/h6-8H,3-5H2,1-2H3;(H2,1,2,3,4)/q+1;/p-1
InChI key
KXCVJPJCRAEILX-UHFFFAOYSA-M
General description
1-Butyl-3-methylimidazolium hydrogen sulfate is an acidic ionic liquid.
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Application
[BMIM][HSO4] can be used as an additive to accelerate current efficiency, lower power consumption, and enhance the surface morphology during the electrodeposition of zinc from acidic sulfate solutions. The combination of sodium nitrate and [BMIM][HSO4] can be used as a nitrating agent for the selective nitration of phenols to afford its corresponding nitro derivatives. [BMIM][HSO4] can also be used as catalyst for the preparation of 1,8-dioxo-octahydroxanthenes.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
543.2 °F
Flash Point(C)
284 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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1-Butyl-3-methylimidazolium Hydrogen Sulfate [Bmim]HSO4: An Efficient Reusable Acidic Ionic Liquid for the Synthesis of 1, 8-Dioxo-Octahydroxanthenes.
J. Chin. Chem. Soc., 56(3), 659-665 (2009)
Bioresource technology, 325, 124726-124726 (2021-01-25)
Quantitative recovery is necessary for scale-up application of acidic ionic liquids (AILs). Ultrafiltration and bipolar membrane electrodialysis (BMED) was employed for the recovery and regeneration of acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulphate (Bmim[HSO4]) after biomass pretreatment. Ultrafiltration was designed for
Using acidic ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate in selective nitration of phenols under mild conditions.
Org. React., 5, 9-9 (2009)
Talanta, 197, 522-529 (2019-02-18)
The cyclic voltammetric behaviour of propionaldehyde (PA) and hexanaldehyde (HA), in 1-butyl-3-methylimidazolium bis(trifluoromethyl-sulfonyl) imide ([BMIM][NTF2]), 1-butyl-3-methylimidazolium hydrogen sulphate ([BMIM][HSO4]) and 1-butyl-3-methylimidazolium hydroxide ([BMIM][OH]) was investigated at a platinum microelectrode. A clear oxidation process for both aldehydes was recorded only in
Effects of 1-butyl-3-methylimidazolium hydrogen sulfate-[BMIM]HSO4 on zinc electrodeposition from acidic sulfate electrolyte.
J. Appl. Electrochem., 39(2), 261-261 (2009)
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