373761
2,2,2-Trifluoroethyl methacrylate
contains 50-200 ppm MEHQ as inhibitor, 99%
Synonym(s):
2,2,2-Trifluoroethyl 2-methylprop-2-enoate
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About This Item
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Quality Level
Assay
99%
form
liquid
contains
50-200 ppm MEHQ as inhibitor
refractive index
n20/D 1.361 (lit.)
bp
59 °C/100 mmHg (lit.)
density
1.181 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
CC(=C)C(=O)OCC(F)(F)F
InChI
1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChI key
QTKPMCIBUROOGY-UHFFFAOYSA-N
General description
2,2,2-Trifluoroethyl methacrylate (TFEMA) is a semifluorinated monomer that can be synthesized from methacryloyl chloride and 2,2,2-trifluoroethanol in presence of triethylamine. Its properties include chemical inertness, good wear resistance and low dielectric constant.
Application
TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
62.6 °F - closed cup
Flash Point(C)
17 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The kinetic polymerization behavior of 2,2,2-trifluoroethyl methacrylate (TFEMA), 1,1,1,3,3,3-hexafluoroisopropyl methacrylate (HFIPMA), 2,2,2-trifluoroethyl acrylate (TFEA) and 1,1,1,3,3,3-hexafluoroisopropyl acrylate (HFIPA) was determined by isothermal differential scanning calorimetry (DSC) and high-performance liquid chromatography (HPLC) in order to improve the properties of fluorinated powder-liquid
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