179647
Silver carbonate
99%
Synonym(s):
Disilver carbonate, Fetizon′s reagent, Silver tricarbonate
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About This Item
Linear Formula:
Ag2CO3
CAS Number:
Molecular Weight:
275.75
Beilstein:
6936654
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
Assay:
99%
form:
powder and chunks
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Quality Level
Assay
99%
form
powder and chunks
reaction suitability
reagent type: catalyst
core: silver
mp
210 °C (dec.) (lit.)
density
6.08 g/mL at 25 °C (lit.)
SMILES string
[Ag]OC(=O)O[Ag]
InChI
1S/CH2O3.2Ag/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2
InChI key
KQTXIZHBFFWWFW-UHFFFAOYSA-L
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General description
Silver carbonate,prepared by precipitation or ion-exchange method can behave as a visible light sensitive semiconductor photocatalyst.
Application
Silver carbonate (Ag2CO3)promotes the regioselective benzylation of carbohydrate derivatives in high yields. Ag2CO3 can be used as a base for the Pd catalysed oxyarylation of olefins by ortho-iodophenols.It can also be used for Koenigs-Knorr glycosylation.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Palladium-catalyzed oxyarylation of olefins using silver carbonate as the base. Probing the mechanism by electrospray ionization mass spectrometry.
Buarque CD, et al.
Journal of Organometallic Chemistry, 695(18), 2062-2067 (2010)
A novel high-efficiency visible-light sensitive Ag 2 CO 3 photocatalyst with universal photodegradation performances: Simple synthesis, reaction mechanism and first-principles study.
Dong H, et al.
Applied Catalysis. B, Environmental, 134, 46-54 (2013)
Photocatalytic behavior and photo-corrosion of visible-light-active silver carbonate/titanium dioxide.
Wang Y, et al
Materials Letters, 115, 85-88 (2014)
V Pacheco-Fowler et al.
The Journal of hospital infection, 57(2), 170-174 (2004-06-09)
The effect of endotracheal tubes (ETTs) impregnated with chlorhexidine (CHX) and silver carbonate (antiseptic ETTs) against Staphylococcus aureus, methicillin-resistant S. aureus (MRSA), Pseudomonas aeruginosa, Acinetobacter baumannii, and Enterobacter aerogenes [organisms associated with ventilator-associated pneumonia (VAP)], was evaluated in a laboratory
José M López-Cepero
The journal of histochemistry and cytochemistry : official journal of the Histochemistry Society, 52(2), 211-216 (2004-01-20)
Silver staining methods, when selective, yield a high-contrast and high-resolution image in optical microscopy. A classical method for silver impregnation of mitochondria has been applied to murine tissues and reveals a marked heterogeneity among mitochondria in single cells. This heterogeneity
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