162574
Dimethylglyoxime
ACS reagent, ≥99%
Synonym(s):
DMG, 2,3-Butanedione dioxime, Diacetyldioxime
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About This Item
Linear Formula:
CH3C(=NOH)C(=NOH)CH3
CAS Number:
Molecular Weight:
116.12
Beilstein:
506731
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.21
Recommended Products
grade
ACS reagent
Quality Level
Assay
≥99%
form
liquid
impurities
≤0.05% insol. Alcohol
ign. residue
≤0.05%
mp
240-241 °C (lit.)
suitability
passes test for determination of nickel
SMILES string
CC(=N/O)\C(C)=N\O
InChI
1S/C4H8N2O2/c1-3(5-7)4(2)6-8/h7-8H,1-2H3/b5-3+,6-4+
InChI key
JGUQDUKBUKFFRO-GGWOSOGESA-N
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General description
Dimethylglyoxime(DMG) is a complexing ligand. Dimethylglyoxime forms a number of mixed ligand complexes with N-acetylglycine and various metals such as VO(IV), Ni(II), Zn(II), Pd(II), Cd(II) and Pb(II).
Application
Dimethylglyoxime (DMG) may be used as complexing agent for the quantification of metallic imprurities [cobalt(II) and nickel(II)] in brine (5.5mol/l aqueous solution of sodium chloride) by adsorptive stripping voltammetry. It may be used in the preparation of nickel dimethylglyoxime, a dye complex used for the fabrication of dye-sensitized solar cells.
Dimethylglyoxime may be used as a chelating agent for determining nickel ion in complexes by gravimetric, titrimetric or colorimetric analysis.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Sol. 2
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The basis of the selectivity of dimethylglyoxime as a reagent in gravimetric analysis.
Sharpe AG and Wakefield DB
Journal of the Chemical Society, 281-285 (1957)
Chelating agents in nonaqueous titrimetry.
Brummet BD and Hollweg RM
Analytical Chemistry, 28(4), 448-450 (1956)
Application of adsorptive stripping voltammetry (AdSV) for the analysis of trace metals in brine.
Romanus A, et al.
Fresenius Journal of Analytical Chemistry, 340(6), 363-370 (1991)
Nile Blue and Nickel Organometallic Dyes Applied in Dye-sensitized Solar Cells.
Siami E, et al.
Portugaliae Electrochimica Acta , 33(1), 23-33 (2015)
Preparation and Spectral Properties of Mixed-Ligand Complexes of VO (IV), Ni (II), Zn (II), Pd (II), Cd (II) and Pb (II) with Dimethylglyoxime and N-Acetylglycine.
Shaker SA
Journal of Chemistry, 7(S1), S580-S586 (2010)
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