236306

Allyl chloride

ReagentPlus^®, 99%

• Synonym(s): 3-Chloro-1-propene, Chlorallylene
• Linear Formula: CH₂=CHCH₂Cl
• CAS Number: 107-05-1
• Molecular Weight: 76.52
• Beilstein: 635704
• EC Number: 203-457-6
• MDL number: MFCD00000984
• UNSPSC Code: 12352100
• PubChem Substance ID: 24854161
• NACRES: NA.22

Properties

• vapor density: 2.6 (vs air)
• Quality Level: 100
• vapor pressure: 20.58 psi ( 55 °C); 5.71 psi ( 20 °C)
• product line: ReagentPlus^®
• Assay: 99%
• form: liquid
• expl. lim.: 11.2 %
• refractive index: n20/D 1.414 (lit.)
• bp: 44-46 °C (lit.)
• mp: −130 °C (lit.)
• solubility: alcohol: miscible(lit.); chloroform: miscible(lit.); diethyl ether: miscible(lit.); petroleum ether: miscible(lit.); water: slightly soluble(lit.)
• density: 0.939 g/mL at 25 °C (lit.)
• functional group: alkyl halide; chloro
• storage temp.: 2-8°C
• SMILES string: ClCC=C
• InChI: 1S/C3H5Cl/c1-2-3-4/h2H,1,3H2
• InChI key: OSDWBNJEKMUWAV-UHFFFAOYSA-N

Description

General description

Kinetcis of epoxidation of allyl chloride with hydrogen peroxide has been reported.

Application

Allyl chloride has been employed:

• as precursor for generation of allyl radicals by laser flash photolysis at 193nm
• in the synthesis of α,ω-difunctional chemical intermediates via the cross-metathesis reactions

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS02,GHS08,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H225,H302 + H312 + H332,H315,H319,H335,H341,H351,H373,H400
• Precautionary Statements: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
• Target Organs: Nervous system,Liver,Kidney, Respiratory system
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): -25.6 °F
• Flash Point(C): -32 °C
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves