16571
(+)-3-Bromocamphor
purum, ≥97.0% (sum of enantiomers, GC)
Synonym(s):
endo-(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
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About This Item
Recommended Products
grade
purum
Quality Level
Assay
≥97.0% (sum of enantiomers, GC)
form
solid
optical activity
[α]20/D +136±3°, c = 1% in ethanol
mp
75-77 °C
functional group
bromo
ketone
SMILES string
[H][C@@]12CC[C@@](C)(C(=O)[C@H]1Br)C2(C)C
InChI
1S/C10H15BrO/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6-7H,4-5H2,1-3H3/t6-,7+,10+/m1/s1
InChI key
NJQADTYRAYFBJN-FWWHASMVSA-N
Application
- Insights into the mechanisms of within-species variation in sensitivity to chemicals: A case study using daphnids exposed to CMIT/MIT biocide.: This study investigates the differential sensitivity of daphnids to 2-Methyl-4-isothiazolin-3-one, highlighting the biochemical mechanisms underlying these variations. The findings provide crucial insights for environmental safety assessments (Kim et al., 2023).
Other Notes
Use as chiral building block; Debromo-silylation and -phosphonylation
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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The Journal of Organic Chemistry, 51, 4342-4342 (1986)
Tetrahedron, 41, 93-93 (1985)
Canadian Journal of Chemistry, 65, 1-1 (1987)
Camphor: a chiral starting material in natural product synthesis.
Natural product reports, 2(3), 253-289 (1985-06-01)
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