398276

Diisopropyl ether

contains either BHT or hydroquinone as stabilizer, ACS reagent, ≥99.0%

• Sinónimos: Isopropyl ether
• Fórmula lineal: (CH₃)₂CHOCH(CH₃)₂
• Número de CAS: 108-20-3
• Peso molecular: 102.17
• Beilstein: 1731256
• Número CE: 203-560-6
• Número MDL: MFCD00008880
• Código UNSPSC: 12191502
• ID de la sustancia en PubChem: 329755910
• NACRES: NA.07
• bp: 68-69 °C (lit.)

Propiedades

• grado: ACS reagent
• Nivel de calidad: 200
• densidad de vapor: 3.5 (vs air)
• presión de vapor: 120 mmHg ( 20 °C)
• Ensayo: ≥99.0%
• Formulario: liquid
• temp. de autoignición: 827 °F
• contiene: either BHT or hydroquinone as stabilizer
• lim. expl.: 1-21 %, 100 °F
• impurezas: ≤0.0007 meq/g Titr. acid; ≤0.05% Peroxide (as C₆H₁₄O₂)
• residuo de evap.: ≤0.01%
• color: APHA: ≤25
• índice de refracción: n20/D 1.367 (lit.)
• bp: 68-69 °C (lit.)
• mp: −85 °C (lit.)
• densidad: 0.725 g/mL at 25 °C (lit.)
• cadena SMILES: CC(C)OC(C)C
• InChI: 1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3
• Clave InChI: ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

Descripción

Descripción general

Diisopropyl ether (DIPE) is branched ether. It is a peroxide forming solvent. This process is catalyzed by heat, light and oxygen. For such solvents small amount of stabilizers like BHT (butylated hydroxytoluene) or hydroquinone is added which removes the free radicals that form peroxides. DIPE has been proposed as a potential alternative oxygenated fuel additive. Several methods have been proposed for its synthesis using acetone as starting material. The molecular structure and conformation has been studied using gas-phase electron diffusion. Its potential carcinogenicity has been studied in Sprague-Dawley rats.

Aplicación

Diisopropyl ether may be used as a solvent in the following processes:

• Resolution of secondary alcohols.
• Enantioselective acylation of 1-phenethylamine.
• Synthesis of aliphatic and aromatic cyanohydrins.

Información de seguridad

• Pictogramas: GHS02,GHS07
• Palabra de señalización: Danger
• Frases de peligro: H225,H336
• Consejos de prudencia: P210 - P233 - P240 - P241 - P242 - P243
• Clasificaciones de peligro: Flam. Liq. 2 - STOT SE 3
• Órganos de actuación: Central nervous system
• Riesgos supl.: EUH019,EUH066
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): -20.2 °F - closed cup
• Punto de inflamabilidad (°C): -29 °C - closed cup