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Merck

207934

Sigma-Aldrich

Tetrafluoroboric acid solution

48 wt. % in H2O

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About This Item

Fórmula lineal:
HBF4
Número de CAS:
Peso molecular:
87.81
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21
concentration:
46.0-52.0% in NaOH (titration)
48 wt. % in H2O

vapor density

3 (vs air)

Quality Level

vapor pressure

5 mmHg ( 20 °C)

form

liquid

concentration

46.0-52.0% in NaOH (titration)
48 wt. % in H2O

density

1.4 g/mL at 25 °C

SMILES string

F.FB(F)F

InChI

1S/BF3.FH/c2-1(3)4;/h;1H

InChI key

LEMQFBIYMVUIIG-UHFFFAOYSA-N

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General description

Tetrafluoroboric acid is used as a catalyst for the protection and deprotection reactions of various carbohydrates. It participates in the synthesis of 4-sulfonic acid phenyl diazonium tetrafluoroborate, which was required for the preparation of sulfonated graphene (SG).

Application

Tetrafluoroboric acid solution may be used as a catalyst for the hydration of aromatic haloalkynes to α-halomethyl ketones in the absence of metal catalysts. It may also be used the epoxidized soybean oil (ESBO) ring opening step of fatty acids preparation.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Tetrafluoroboric acid, an efficient catalyst in carbohydrate protection and deprotection reactions.
Albert R, et al.
Carbohydrate Research, 137, 282-290 (1985)
Polyols and polyurethanes prepared from epoxidized soybean oil ring-opened by polyhydroxy fatty acids with varying OH numbers.
Chen R, et al.
Journal of Applied Polymer Science, 132(1) (2015)
M P Dariel et al.
Dental materials : official publication of the Academy of Dental Materials, 11(3), 208-217 (1995-05-01)
The purpose of this study was to develop a new technology for preparing mercury-free metallic dental restorative materials. The novel approach relies on the cold welding of surface treated silver particles. At ambient temperature, intermetallic compound formation takes place spontaneously
Arnis Abolins et al.
Materials (Basel, Switzerland), 14(4) (2021-03-07)
A second-generation bio-based feedstock-tall oil fatty acids-was epoxidised via two pathways. Oxirane rings were introduced into the fatty acid carbon backbone using a heterogeneous epoxidation catalyst-ion exchange resin Amberlite IR-120 H or enzyme catalyst Candida antarctica lipase B under the
Gary A Molander et al.
Organic letters, 12(21), 4876-4879 (2010-10-01)
Amidomethyltrifluoroborates were successfully synthesized in a one-pot fashion and used in cross-coupling reactions with a wide variety of aryl and heteroaryl chlorides.

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