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Merck

13245

Sigma-Aldrich

Manganese(II) sulfate monohydrate

puriss., meets analytical specification of Ph. Eur, BP, USP, FCC, 99-100.5% (calc. for dried substance)

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About This Item

Fórmula lineal:
MnSO4 · H2O
Número de CAS:
Peso molecular:
169.02
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
assay:
99-100.5% (calc. for dried substance)
form:
powder or crystals

grade

puriss.

Quality Level

assay

99-100.5% (calc. for dried substance)

form

powder or crystals

quality

meets analytical specification of Ph. Eur, BP, USP, FCC

impurities

organic volatile impurities, complies (GC)
residual solvents, complies
≤0.002% heavy metals (as Pb)
≤0.5% matter not precip. by ammonia sol.

loss

10-12% loss on ignition, 500 °C

pH

3-3.5 (20 °C, 50 g/L)

anion traces

chloride (Cl-): ≤100 mg/kg

cation traces

As: ≤3 mg/kg
Ca: ≤200 mg/kg
Fe: ≤10 mg/kg
Mg: ≤200 mg/kg
Pb: ≤4 mg/kg
Se: ≤30 mg/kg
Zn: ≤50 mg/kg

suitability

complies for appearance of solution

SMILES string

O.[Mn++].[O-]S([O-])(=O)=O

InChI

1S/Mn.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+2;;/p-2

InChI key

ISPYRSDWRDQNSW-UHFFFAOYSA-L

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General description

Manganese (II) sulfate monohydrate is a safe and inexpensive catalyst used in organic synthesis. Additionally, it is used to prepare manganese dioxide and manganese.

Application

Manganese (II) sulfate monohydrate is used:
  • As a catalyst in the synthesis of heterocyclic compounds such as benzo-2-pyrones and benzopyrazines.
  • To prepare cathode material magnesium manganese spine (MgMn2O4) by coprecipitation method.

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 Inhalation

target_organs

Brain

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable


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Zhehui Weng et al.
Inorganic chemistry, 48(18), 8703-8708 (2009-08-25)
A new glycine-templated manganese(II) sulfate, (C(2)NO(2)H(5))MnSO(4) (1), has been solvothermally synthesized and characterized crystallographically and magnetically. Crystal data for 1: monoclinic, space group P2(1)/m, a = 4.8884(10) A, b = 7.8676(14) A, c = 8.0252(15) A, beta = 106.524(2) degrees
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