ALD00108

3,6-Bis(methylthio)-1,2,4,5-tetrazine

≥95% (HPLC)

• Sinónimos: 3,6-Bis(methylthio)-s-tetrazine, NSC 674352, s-Tetrazine
• Fórmula empírica (notación de Hill): C₄H₆N₄S₂
• Número de CAS: 1672-34-0
• Peso molecular: 174.25
• MDL number: MFCD02998583
• UNSPSC Code: 12352100
• PubChem Substance ID: 329772592
• NACRES: NA.22

Propiedades

• Quality Level: 100
• assay: ≥95% (HPLC)
• form: powder
• mp: 82-87 °C
• storage temp.: −20°C
• SMILES string: CSC1=NN=C(SC)N=N1
• InChI: 1S/C4H6N4S2/c1-9-3-5-7-4(10-2)8-6-3/h1-2H3
• InChI key: ROUDTSAXQIBBFZ-UHFFFAOYSA-N

Descripción

Application

3,6-Bis(methylthio)-1,2,4,5-tetrazine can be used as a versatile building block in the inverse elecron demand hetero Diels-Alder reactions. The Boger Research Group has reported this powerful approach in the synthesis of alkaloids.
It can also used to synthesize:

• Substituted indoles and indolines derivatives by sequential [4+2] cycloaddition reactions.
• 3-(Methylthio)-6-(4-morpholinyl)-1,2,4,5-tetrazine by aromatic nucleophilic substitution reaction.

Other Notes

Total Synthesis of Amaryllidaceae Alkaloids Utilizing Sequential Intramolecular Heterocyclic Azadiene Diels-Alder Reactions of an Unsymmetrical 1, 2, 4, 5-Tetrazin

Regioselective Inverse Electron Demand Diels-Alder Reactions of N-Acyl 6-Amino-3-(methylthio)-1, 2, 4, 5-tetrazines

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable