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Merck

32851

Sigma-Aldrich

trans-1,4-Diaminocyclohexane

≥98.0% (GC)

Sinónimos:

trans-1,4-Cyclohexanediamine

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About This Item

Fórmula lineal:
C6H10(NH2)2
Número de CAS:
Peso molecular:
114.19
Beilstein/REAXYS Number:
2801657
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
assay:
≥98.0% (GC)

vapor pressure

18 mmHg ( 87.2 °C)

assay

≥98.0% (GC)

autoignition temp.

680 °F

expl. lim.

6 %

bp

197 °C (lit.)

mp

68-72 °C (lit.)

SMILES string

N[C@H]1CC[C@H](N)CC1

InChI

1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6-

InChI key

VKIRRGRTJUUZHS-IZLXSQMJSA-N

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Application

trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 4 Oral - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 2

flash_point_f

159.8 °F - closed cup

flash_point_c

71 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Mohammad S Ali et al.
Journal of inorganic biochemistry, 96(4), 452-456 (2003-09-19)
A series of new platinum(II) and platinum(IV) adducts of type [P(II)(cis-1,4-DACH)LCl]NO(3,) where cis-1,4-DACH=cis-1,4-diaminocyclohexane, and L=9-ethylguanine, 1-methylcytosine, adenine, adenosine, cytosine, cytidine, guanine, and [Pt(IV)(cis-1,4-DACH)Ltrans-(X)(2)Cl]NO(3), (where Y=hydroxo or acetato), were synthesized and characterized by elemental analysis, infrared spectroscopy, and 1H and 195Pt
Han Wang et al.
Small (Weinheim an der Bergstrasse, Germany), 16(42), e2003098-e2003098 (2020-10-01)
The crystalline orientation and phase distribution are two important parameters for high-performance 2D perovskite solar cells. Therefore, it is essential to understand how the structure of spacer ligands influences the orientation and phase distribution of resulting 2D perovskite films. In
T A Grigolo et al.
Dalton transactions (Cambridge, England : 2003), 46(45), 15698-15703 (2017-10-31)
Herein we describe the high yield synthesis of a highly crystalline cobalt(ii) MOF with a novel zwitterionic ligand made up of 3,3',4,4'-BPTC and 1,4-cyclohexanediamine, obtained in situ during the hydrothermal synthesis. The compound with the molecular formula C
Shalini Balakrishnan et al.
The Journal of organic chemistry, 72(25), 9834-9837 (2007-11-06)
To introduce chirality and functional groups adjacent to guanidiniums to modulate specificity and affinity in recognition, N,N'-bis(Boc)-alpha-guanidino acids were synthesized from alpha-amino acid methyl esters. Protected alpha-guanidino acids coupled to cyclohexylamine and trans-1,4-diaminocyclohexane in good yield and with retention of
F Vianello et al.
Protein expression and purification, 15(2), 196-201 (1999-03-02)
A novel, simple, and rapid procedure for the purification of pea seedling amine oxidase is reported. The crude enzyme, obtained by ammonium sulfate fractionation, was purified in two steps: the first one by anion-exchange chromatography and the second one by

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