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171441

Sigma-Aldrich

Trifluoroiodomethane

99%

Sinónimos:

Iodotrifluoromethane, Perfluoromethyl iodide, Trifluoromethyl iodide

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About This Item

Fórmula empírica (notación de Hill):
CF3I
Número de CAS:
2314-97-8
Peso molecular:
195.91
Beilstein/REAXYS Number:
1732740
EC Number:
219-014-5
MDL number:
MFCD00001060
UNSPSC Code:
12142100
PubChem Substance ID:
24850061
NACRES:
NA.22

Quality Level

100

assay

99%

bp

−22.5 °C (lit.)

mp

<−78 °C (lit.)

functional group

fluoro
iodo

SMILES string

FC(F)(F)I

InChI

1S/CF3I/c2-1(3,4)5

InChI key

VPAYJEUHKVESSD-UHFFFAOYSA-N

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Categorías relacionadas

Application

Reagent used in the rhodium-catalyzed α-trifluoromethylation of α,ß-unsaturated ketones.

Packaging

Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

Hose barb

Referencia del producto
Descripción
Precios

Z146811

Hose adapter, brass

Optional

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Regulator

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Descripción
Precios

Z513539

Aldrich® mini gas regulator, brass body

also commonly purchased with this product

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Descripción
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Z221880

PTFE sealing tape, W 1 in.

Z104388

PTFE sealing tape, W 1/2 in.

signalword

Warning

Hazard Classifications

Muta. 2 - Ozone 1 - Press. Gas Compr. Gas

Storage Class

2A - Gases

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
SHBJ8355
BCBR8746V
SHBC3558V
SHBB7146V
34296KK

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D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced
A Vinegar et al.
Inhalation toxicology, 12(8), 751-763 (2000-07-06)
Most proposed replacements for Halon 1301 as a fire suppressant are halogenated hydrocarbons. The acute toxic endpoint of concern for these agents is cardiac sensitization. An approach is described that links the cardiac endpoint as assessed in dogs to a
G Hancock et al.
Physical chemistry chemical physics : PCCP, 9(18), 2234-2239 (2007-05-10)
Frequency modulated diode laser based absorption at 1.315 microm has been used to measure the Doppler lineshapes of the I((2)P(1/2)-(2)P(3/2)) transition in atomic iodine produced from the 266 nm photolysis of both CF(3)I and C(2)F(5)I. Wavelength resolved laser gain is
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Artículos

Tetrakis(dimethylamino)ethylene (TDAE)

In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)

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