921750
endo-N-Methyl-5-norbornene-2-carboxamide
≥95%
Synonym(s):
endo-N-Methylbicyclo[2.2.1]hept-5-ene-2-carboxamide
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About This Item
Empirical Formula (Hill Notation):
C9H13NO
CAS Number:
Molecular Weight:
151.21
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
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Application
endo-N-Methyl-5-norbornene-2-carboxamide is a norbornene ligand developed in the lab of Guanbing Dong for use in norbornene/palladium catalysis.
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Product No.
Description
Pricing
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
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Zhe Dong et al.
Angewandte Chemie (International ed. in English), 54(43), 12664-12668 (2015-09-04)
Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.
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