Skip to Content
Merck
All Photos(1)

Key Documents

View All Documentation

662984

Sigma-Aldrich

Potassium cyclopropyltrifluoroborate

≥99%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Empirical Formula (Hill Notation):
C3H5BF3K
CAS Number:
1065010-87-8
Molecular Weight:
147.98
MDL number:
MFCD09265031
UNSPSC Code:
12352103
PubChem Substance ID:
24884175
NACRES:
NA.22

Quality Level

100

Assay

≥99%

form

powder

mp

348-350 °C

SMILES string

[K+].F[B-](F)(F)C1CC1

InChI

1S/C3H5BF3.K/c5-4(6,7)3-1-2-3;/h3H,1-2H2;/q-1;+1

InChI key

CFMLURFHOSOXRC-UHFFFAOYSA-N

Related Categories

General description

May contain 5-10% cyclopropylboronic acid

Application

Organotrifluoroborate involved in Suzuki-Miyaura cross-coupling reactions

Organotrifluoroborates as versatile and stable boronic acid surrogates.

Pictograms

Health hazard
GHS08

Signal Word

Danger

Hazard Statements

H360FD

Hazard Classifications

Repr. 1B

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBJ7063
SHBF0670V
36996BP
46196PM
35696LM

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Charette, A. B. et al.
Synlett, 1779-1779 (2005)
Guo-Hua Fang et al.
Organic letters, 6(3), 357-360 (2004-01-30)
[reaction: see text] Stereospecific cyclopropanation of alkenylboronic esters of pinacol followed by in situ treatment with excess KHF(2) afforded the corresponding potassium cyclopropyl trifluoroborates in high yields, which then underwent Suzuki-Miyaura cross-coupling reactions with aryl bromides to give cyclopropyl-substituted arenes

Articles

Potassium Organotrifluoroborates

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

Potassium Organotrifluoroborates

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

Potassium Organotrifluoroborates

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

Potassium Organotrifluoroborates

Bench-stable Potassium Organotrifluoroborates enable diverse C-C bond formation reactions.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service