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538965

Sigma-Aldrich

Tris(dibenzoylmethane) mono(1,10-phenanthroline)europium(lll)

95%

Synonym(s):

Eu(dbm)3(phen), Europium(III) tris(1,3-diphenyl-1,3-propanedionato) mono(1,10-phenanthroline)

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About This Item

Empirical Formula (Hill Notation):
C57H41EuN2O6
CAS Number:
17904-83-5
Molecular Weight:
1001.91
MDL number:
MFCD01321202
UNSPSC Code:
12352103
PubChem Substance ID:
24878371
NACRES:
NA.23

Quality Level

100

Assay

95%

reaction suitability

reagent type: catalyst
core: europium

mp

185-191 °C (lit.)

λmax

228 nm

fluorescence

λex 355 nm; λem 615 nm in THF

OLED Device Performance

ITO/PEDOT:PSS/PVK:Eu(dbm)3(Phen)/Ca:Al

  • Color: red
  • Max. Luminance: 130 Cd/m2
  • Max. EQE: 0.03 %

SMILES string

c1cnc2c(c1)ccc3cccnc23.O=C(\C=C(\O[Eu](O\C(=C\C(=O)c4ccccc4)c5ccccc5)O\C(=C\C(=O)c6ccccc6)c7ccccc7)c8ccccc8)c9ccccc9

InChI

1S/3C15H12O2.C12H8N2.Eu/c3*16-14(12-7-3-1-4-8-12)11-15(17)13-9-5-2-6-10-13;1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h3*1-11,16H;1-8H;/q;;;;+3/p-3/b3*14-11+;;

InChI key

VFVBZVBAWCSCIO-RWBKAWJDSA-K

General description

Light emitting metal complex.

Application

Luminescent complexes of Eu(dbm)3phen, β-diketonate Eu(dbm)3phen were loaded on mesoporous silica nanoparticles in a series of concentrations, to study their use as a spectral converter for a multi-crystalline silicon solar cell. This product may be used as a constituent in the preparation of an aqueous micellar anionic surfactant solution to dye anodic porous alumina. Eu(DBM)3Phen is used as an emitter.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP6836
SHBP5010
SHBN3174
MKCJ6380
MKCG0732

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Concentration quenching and photostability in Eu (dbm) 3 phen embedded in mesoporous silica nanoparticles.
Moretti E, et al.
Journal of Luminescence null
Narrow bandwidth red electroluminescence from solution-processed lanthanide-doped polymer thin films
O'Riordan, A.; et al.
Thin Solid Films, 491, 264 - 269 (2005)
Concentration quenching and photostability in Eu (dbm) 3 phen embedded in mesoporous silica nanoparticles.
Moretti E, et al.
Journal of Luminescence, 178-185 null
Enhancement of Light Emission from an Europium (III) Complex Based-OLED by Using Layer-By-Layer Assembled Hole-Transport Films.
Santos G, et al.
ECS Transactions, 307-313 null
Enhancement of Light Emission from an Europium (III) Complex Based-OLED by Using Layer-By-Layer Assembled Hole-Transport Films.
Santos G, et al.
ECS Transactions null
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