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Quality Level
Assay
98%
form
liquid
refractive index
n20/D 1.595 (lit.)
bp
181-182 °C (lit.)
mp
−5-−3 °C (lit.)
solubility
organic solvents: miscible
water: insoluble
density
0.996 g/mL at 25 °C (lit.)
storage temp.
2-8°C
SMILES string
C1C=Cc2ccccc12
InChI
1S/C9H8/c1-2-5-9-7-3-6-8(9)4-1/h1-6H,7H2
InChI key
YBYIRNPNPLQARY-UHFFFAOYSA-N
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General description
Indene is oxidized to mixtures of cis- and trans-indandiols and related metabolites by Pseudomonas putida and Rhodococcus sp.
Application
Indene was used in the synthesis of new C60 derivative, indene-C60 bisadduct. It was used in preparing polyindene by the controlled cationic polymerization initiated with cumyl methyl ether/TiCl4 in CH2Cl2.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 3
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
136.4 °F - closed cup
Flash Point(C)
58 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Metabolic engineering, 1(1), 63-74 (2000-08-10)
Indene is oxidized to mixtures of cis- and trans-indandiols and related metabolites by Pseudomonas putida and Rhodococcus sp. isolates. Indene metabolism is consistent with monooxygenase and dioxygenase activity. P. putida resolves enantiomeric mixtures of cis-1,2-indandiol by further selective oxidation of
High glass transition temperature polyolefins obtained by the catalytic hydrogenation of polyindene.
Macromolecules, 36(1), 71-76 (2003)
Applied microbiology and biotechnology, 85(4), 995-1004 (2009-07-02)
The styAB genes from Pseudomonas putida CA-3, which encode styrene monooxygenase, were subjected to three rounds of in vitro evolution using error-prone polymerase chain reaction with a view to improving the rate of styrene oxide and indene oxide formation. Improvements
Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes.
Angewandte Chemie (International ed. in English), 50(18), 4169-4172 (2011-03-31)
Organic letters, 10(21), 4855-4857 (2008-10-07)
A new methodology for the preparation of substituted naphthalenes starting from readily available indenones, organometal reagents, and trimethylsilyldiazomethane via a catalytic rearrangement process is described. Hindered biaryl naphthalenes, including triortho-substituted biaryls, can be accessed through our method. Our results are
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