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10029

Sigma-Aldrich

Mercury(II) sulfate

puriss., ≥98%

Synonym(s):

Mercuric sulfate

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250 G
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250 G
€266.00
1 KG
€737.00
6 X 250 G
€1,250.00

About This Item

Linear Formula:
HgSO4
CAS Number:
Molecular Weight:
296.65
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.55
form:
powder or crystals

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grade

puriss.

Assay

≥98%

form

powder or crystals

ign. residue (after red. with HCOOH)

≤0.1% (as SO4)

anion traces

chloride (Cl-): ≤50 mg/kg

cation traces

Fe: ≤50 mg/kg

SMILES string

[Hg++].[O-]S([O-])(=O)=O

InChI

1S/Hg.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2

InChI key

DOBUSJIVSSJEDA-UHFFFAOYSA-L

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Application

Mercury(II) sulfate can be used as a catalyst in the presence of sulfuric acid (H2SO4) for the:
  • Direct oxidation of methane to methanol.
  • Hydration of alkynes to the corresponding carbonyl compounds.
  • Conversion of alkyl protected glycals into their corresponding α,β-unsaturated enals (Perlin aldehydes).

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Target Organs

Kidney

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

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Certificates of Analysis (COA)

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Laurie F Caslake et al.
Applied and environmental microbiology, 70(2), 1145-1150 (2004-02-10)
Contaminated water causes an estimated 6 to 60 billion cases of gastrointestinal illness annually. The majority of these cases occur in rural areas of developing nations where the water supply remains polluted and adequate sanitation is unavailable. A portable, low-cost
Tariq SA and Hill JO.
J. Therm. Anal., 212, 277-281 (1981)
Catalysis by mercuric ion of reactions of glycals with water.
Gonzalez F, et al.
Carbohydrate Research, 42(2), 267-274 (1975)
Direct oxidation of methane to methanol by mercuric sulfate catalyst.
Gang X, et al.
J. Catal., 196(2), 287-292 (2000)
A P de Souza et al.
Dental materials : official publication of the Academy of Dental Materials, 16(2), 103-108 (2001-02-24)
The interaction between metal ions and the oral environment is a major subject matter in dental research. Matrix metalloproteinases (MMPs) have been implicated in several pathologic oral processes such as periodontal tissue destruction, root caries, tumour invasion and temporomandibular joint

Questions

  1. Please, I need to know the expired date of this chemical: Mercury (II) sulfate CAS number 7783-35-9, batch number: BCCF1405, product number: 10029, Quality release date: 27 NOV 2020

    1 answer
    1. This product does not contain an expiration date. This product contains a recommended retest date of roughly 2 years. A recommended retest date is the period of time during which the product is expected to remain within established stability specifications, provided that it has been stored under defined conditions. After the Retest Date, product samples should be examined to ensure that the product is still in compliance with the established specifications. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

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